Electron transfer between exited cresyi violet (cv+)‎ dye and Semiconductors at a cetonitrile solvent

Abstract EN

The Calculation of the rate constant of electron transfer reaction is demonstrated for interfacial electron transfer from the excited cresol violet (CI!) dye molecule to the conduction band of Tin Dioxide (5<

The reorganization (energies).

And the ^driving free energies AG* were calculated when it is assumed that the electron transfer from the I ^excited dye molecule to the acceptor states in the conduction band of the semiconductors is 1ilt *proportional to the concentration of the electron at the interface surfaces.

In accordance with a weak pulping approximation, the coupling matrix element V can be expressed as a coupling of the wave-actions between excited state molecule dye and the acceptor state of semiconductors.

The result of tron ; transfer studies show that the electron transfer is effective in ITO/CV dye system than $2 / fV at a acetonitrile solvent.