Synthesis and characterization of novel tetradentate ligand type N4 and its complexes with CoII, NiII, and PdII
Other Title(s)
N4نوع تحضير و تشخيص ليكاند رباعي السن جديد و معقداته مع CoII, NiII and PdII
Author
Source
Ibn al-Haitham Journal for Pure and Applied Science
Issue
Vol. 22, Issue 4 (31 Dec. 2009)12 p.
Publisher
University of Baghdad College of Education for Pure Science / Ibn al-Haitham
Publication Date
2009-12-31
Country of Publication
Iraq
No. of Pages
12
Main Subjects
Abstract AR
تضمن البحث تحضير الليكاند الجديد [H2L] الذي يمثل :- [2,3,8,9-tetra-phenyl-1,4,5,7,10,12-hexaazo-5,12-dihydro-6,11-dione-1,3,7,10-dudec tetra- ene] بخطوتين : الخطوة الأولى مفاعلة (benzil) مع (semicarbazidhydrochlorid) و تكوين [benzil bis -(Semicarbazone)] و الخطوة الثانية مفاعلة ناتج الخطوة الأولى مع (benzil) لتحضير الليكاند الجديد [H2L] ثم مفاعلة [H2L] مع كل من CoII, NiII and PdII الليكاند و باستعمال الميثانول وسطا للتفاعل و بنسبة (1:1) للحصول على معقدات جديدة ذوات الصيغة العامة : [M (H2L)]Cl2 إذ : M = CoII, NiII and PdII شخصت جميع المركبات المحضرة بالطرائق الطيفية الآتية : (الأشعة تحت الحمراء، و الأشعة فوق البنفسجية-المرئية، و مطيافية الامتصاص الذري للعناصر) و محتوى الكلور و درجات الانصهار، مع قياس التوصيلية المولارية الكهربائية.
من نتائج التقنيات السابقة فإن الشكل الفراغي المقترح لمعقدات الكوبالت و النيكل هو رباعي السطوح المشوه، بينما يتخذ البلاديوم شكل مربع مستو.
Abstract EN
A new Schiff base ligand [2, 3, 8, 9–tetra phenyl-1, 4, 5, 7, 10, 12-hexa azo-5, 12- dihydro -6, 11- dione 1, 3, 7, 10-dudec-tetra-ene] [H2L] and its complexes In general formula [M(H2L)]Cl2 (where : M = CoII, NiII, and PdII) were prepared.
This ligand was prepared in two steps,in the first step a solution of benzil in methanol was reacted under reflux with semicarbazidhydrochlorid to give an (intermediate compound)[benzyl bis–Semicarbazone)] which was reacted in the second step with benzil giving the mentioned ligand.
The complexes CoII, NiII, and PdII were synthesized by direct reaction of the corresponding metal chloride with the ligand [H2L].The ligand and complexes were characterized by spectroscopic methods (IR, UV-Vis, and atomic absorption), chloride content and conductivity measurement.
From the data of these measurements, we suggestred a tetrahedral geometry for CoII, NiII complexs and a square planar for PdII complex.
American Psychological Association (APA)
Yusuf, Inam Ismail. 2009. Synthesis and characterization of novel tetradentate ligand type N4 and its complexes with CoII, NiII, and PdII. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 22, no. 4.
https://search.emarefa.net/detail/BIM-287705
Modern Language Association (MLA)
Yusuf, Inam Ismail. Synthesis and characterization of novel tetradentate ligand type N4 and its complexes with CoII, NiII, and PdII. Ibn al-Haitham Journal for Pure and Applied Science Vol. 22, no. 4 (2009).
https://search.emarefa.net/detail/BIM-287705
American Medical Association (AMA)
Yusuf, Inam Ismail. Synthesis and characterization of novel tetradentate ligand type N4 and its complexes with CoII, NiII, and PdII. Ibn al-Haitham Journal for Pure and Applied Science. 2009. Vol. 22, no. 4.
https://search.emarefa.net/detail/BIM-287705
Data Type
Journal Articles
Language
English
Notes
Includes appendices.
Record ID
BIM-287705