Synthesis and characterization of (Fe(II), Co (II), Ni (II) and Cu (II)) complexes with schiff base derived from [benzoyl hydrazine] with [benzyl mono oxime]
Other Title(s)
تحضير و تشخيص معقدات ثلاثي المنح نوع N2O من تفاعل الليكاند Benzoic acid (2-hydroxy imino – 1,2-di Phyneyl ethylidene)-hydrazide مع ايونات العناصر (Fe (п), Co (п), Ni (п), and Cu (п))
Joint Authors
al-Salihi, Iman Ibrahim Abd al-Karim
al-Husayni, Ahmad Thabit Numan Husayn
Muhammad, Suhad Shakir
Source
Issue
Vol. 6, Issue 4 (31 Dec. 2009), pp.748-756, 9 p.
Publisher
University of Baghdad College of Science for Women
Publication Date
2009-12-31
Country of Publication
Iraq
No. of Pages
9
Main Subjects
Topics
Abstract AR
حضر الليكاند [Benzoic acid (2-hydroxyimino- 1,2-diphyneylethylidene)- hydrazide] من مفاعلة (Benzoylhydrazine) مع (Diphenylmonooxime) ثم مفاعلة الليكاند مع بعض العناصر الفلزية باستخدام الميثانول وسطا للتفاعل و بنسبة (1 : 1) بوجود حامض الخليك حيث تكونت معقدات جديدة ذوات الصيغة العامة : [M (L) Cl2 H2O] حيث : M= Fe (11), Co (11), Ni (11), and Cu (11) شخصت جميع المركبات بالطرق الطيفية التالية (الأشعة تحت الحمراء و الأشعة فوق البنفسجية – المرئية و كذلك شخصت المركبات بوساطة، التحليل الكمي الدقيق للعناصر مع التوصيلية المولارية الكهربائية).
من نتائج البحث كان الشكل الفراغي المقترح لمعقدات العناصر هي ثماني السطوح.
Abstract EN
The reaction of [Benzoyl hydrazine] with [Diphenyl mono oxime] and Glacial acetic acid was carried out in methanol gave a new tridentate ligand [Benzoic acid (2-hydroxyimino- 1, 2-diphyneylethylidene) - hydrazide].
This ligand was reacted with some metal ions (Fe(II), Co(II), Ni(II), and Cu(II)) in methanol with (1:1) metal : ligand ratio to give a series of new complexes of the general formula [M(L)Cl2.H2O], where M= Fe(11), Co(11), Ni(11) and Cu(11).
All compounds were characterized by spectroscopic methods (I.R, UV-Vis), elemental microanalysis (C.H.N), atomic absorption, magnetic susceptibility, and conductivity measurements.
From the obtained data the proposed molecular structures were suggested for the complexes of Fe (II), Co (II), Ni (II) and Cu (II) are of geometric octahedral.
American Psychological Association (APA)
al-Husayni, Ahmad Thabit Numan Husayn& Muhammad, Suhad Shakir& al-Salihi, Iman Ibrahim Abd al-Karim. 2009. Synthesis and characterization of (Fe(II), Co (II), Ni (II) and Cu (II)) complexes with schiff base derived from [benzoyl hydrazine] with [benzyl mono oxime]. Baghdad Science Journal،Vol. 6, no. 4, pp.748-756.
https://search.emarefa.net/detail/BIM-353930
Modern Language Association (MLA)
al-Husayni, Ahmad Thabit Numan Husayn…[et al.]. Synthesis and characterization of (Fe(II), Co (II), Ni (II) and Cu (II)) complexes with schiff base derived from [benzoyl hydrazine] with [benzyl mono oxime]. Baghdad Science Journal Vol. 6, no. 4 (Dec. 2009), pp.748-756.
https://search.emarefa.net/detail/BIM-353930
American Medical Association (AMA)
al-Husayni, Ahmad Thabit Numan Husayn& Muhammad, Suhad Shakir& al-Salihi, Iman Ibrahim Abd al-Karim. Synthesis and characterization of (Fe(II), Co (II), Ni (II) and Cu (II)) complexes with schiff base derived from [benzoyl hydrazine] with [benzyl mono oxime]. Baghdad Science Journal. 2009. Vol. 6, no. 4, pp.748-756.
https://search.emarefa.net/detail/BIM-353930
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 754-755
Record ID
BIM-353930