Synthesis and characterization of tetradentate complexes type N2O2 from the reaction of 2-hydroxy -1, 2-diphynel-ethanone Oxime [H2L] With Mn II, Fe II, Co II, Ni II, Cu II and Hg II Ions
Other Title(s)
تحضير و تشخصيص معتقدات رباعية المنح نوع N2O2 من تفاعل اللينكدhydroxy -1, 2-diphynel-ethanone Oxime [H2L] مع الايونات (Mn II, Fe II, Co II, Ni II, Cu II and Hg II)
Joint Authors
al-Salihi, Iman Ibrahim Abd al-Karim
al-Husayni, Ahmad Thabit Numan Husayn
al-Dulaymi, Jasim Hashim
Source
Ibn al-Haitham Journal for Pure and Applied Science
Issue
Vol. 22, Issue 3 (30 Sep. 2009)11 p.
Publisher
University of Baghdad College of Education for Pure Science / Ibn al-Haitham
Publication Date
2009-09-30
Country of Publication
Iraq
No. of Pages
11
Main Subjects
Topics
- Chemistry
- Organic chemistry
- Spectrometers
- Optics
- Light
- Organic compounds
- Analytical chemistry
- Absorption spectra
Abstract EN
Tetradentate complexes type [M (HL) 2] were prepared from the reaction of 2-hydroxy -1, 2-diphynel-ethanone oxime [H2L] and KOH with ( Mn II, Fe II, Co II, Ni II , Cu II and Hg II ), in methanol with (2:1) metal: ligand ratio.
The general formula for Cu II and Mn II complexes are [M (HL) 2 Cl.H2O] K, for Co II [Co (HL) 2.
H2O] and [M (HL) 2] for the rest of complexes.
All compounds were characterised by sp ectroscopic methods, I.R, U.V-Vis, H.P.L.C, atomic absorption and conductivity measurements chloride content.
From the data of these measurements, the proposed molecular structures for Fe II and Hg II complexes are tetrahedrals, while Mn II and Cu II complexes are octahedrals, Ni II complex adopting square planar structure and the complex of Co II ion showed a bipyramidal structure
American Psychological Association (APA)
al-Husayni, Ahmad Thabit Numan Husayn& al-Salihi, Iman Ibrahim Abd al-Karim& al-Dulaymi, Jasim Hashim. 2009. Synthesis and characterization of tetradentate complexes type N2O2 from the reaction of 2-hydroxy -1, 2-diphynel-ethanone Oxime [H2L] With Mn II, Fe II, Co II, Ni II, Cu II and Hg II Ions. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 22, no. 3.
https://search.emarefa.net/detail/BIM-354508
Modern Language Association (MLA)
al-Husayni, Ahmad Thabit Numan Husayn…[et al.]. Synthesis and characterization of tetradentate complexes type N2O2 from the reaction of 2-hydroxy -1, 2-diphynel-ethanone Oxime [H2L] With Mn II, Fe II, Co II, Ni II, Cu II and Hg II Ions. Ibn al-Haitham Journal for Pure and Applied Science Vol. 22, no. 3 (2009).
https://search.emarefa.net/detail/BIM-354508
American Medical Association (AMA)
al-Husayni, Ahmad Thabit Numan Husayn& al-Salihi, Iman Ibrahim Abd al-Karim& al-Dulaymi, Jasim Hashim. Synthesis and characterization of tetradentate complexes type N2O2 from the reaction of 2-hydroxy -1, 2-diphynel-ethanone Oxime [H2L] With Mn II, Fe II, Co II, Ni II, Cu II and Hg II Ions. Ibn al-Haitham Journal for Pure and Applied Science. 2009. Vol. 22, no. 3.
https://search.emarefa.net/detail/BIM-354508
Data Type
Journal Articles
Language
English
Notes
19
Record ID
BIM-354508