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Synthesis and characterization of novel ligand Type N2O2 and it's complexes with Cu (п) Co (п), Ni (п), Zn (п), and Cd (п) ions
Other Title(s)
تحضير و تشخيص لينكد جديد نوع N2O2 و بعض معقداته مع العناصر الفلزية [Co (п) Cu (п), Ni (п), Zn (п), and Cd (п)]
Joint Authors
al-Salihi, Iman Ibrahim Abd al-Karim
al-Jabburi, Muhammad Jabir
Thabit, Ahmad
Source
Ibn al-Haitham Journal for Pure and Applied Science
Issue
Vol. 22, Issue 2 (30 Jun. 2009)12 p.
Publisher
University of Baghdad College of Education for Pure Science / Ibn al-Haitham
Publication Date
2009-06-30
Country of Publication
Iraq
No. of Pages
12
Main Subjects
Topics
Abstract EN
The reaction of ethylenediamine with [2,4,6-trihydroxyacetophenon] and KOH (Schiff Base) to gives the new tetradentate ligand 2-(1-{2-{1-2,6-Dihydroxy-4-methyl phenyl)- ethyliden amino}- ethylimino}-ethyl-benzene- 1,2,5-triol [HCl].
This ligand was reacted with some metal ions (Cu(II), Co(II), Ni(II), Zn(II), and Cd(II)) in methanol with (1:1) metal : ligand ratio to give a series of new complexes of the general formula [M(H4L)], where: M= Cu(11), Co(II), Ni(II), Zn(II), and Cd(II).
All compounds were characterized by spectroscopic methods [I.R, U.V.-Vis, C.H.N., analysis H.P.L.C, atomic absorption, magnetic susceptibility, (EI-mass for the ligand)], and microanalysis along with conductivity measurements.
From the obtained data the propos ed molecular structure was suggested for [Co(H4L)], [Ni(H4L)], [Cu(H4L)], which are complexes adopting square planar structure, and [Zn(H4L) and [Cd(H4L)] which are complexes adopting a tetrahedral structure about the metal ions respectively.
American Psychological Association (APA)
Thabit, Ahmad& al-Jabburi, Muhammad Jabir& al-Salihi, Iman Ibrahim Abd al-Karim. 2009. Synthesis and characterization of novel ligand Type N2O2 and it's complexes with Cu (п) Co (п), Ni (п), Zn (п), and Cd (п) ions. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 22, no. 2.
https://search.emarefa.net/detail/BIM-354900
Modern Language Association (MLA)
Thabit, Ahmad…[et al.]. Synthesis and characterization of novel ligand Type N2O2 and it's complexes with Cu (п) Co (п), Ni (п), Zn (п), and Cd (п) ions. Ibn al-Haitham Journal for Pure and Applied Science Vol. 22, no. 2 (2009).
https://search.emarefa.net/detail/BIM-354900
American Medical Association (AMA)
Thabit, Ahmad& al-Jabburi, Muhammad Jabir& al-Salihi, Iman Ibrahim Abd al-Karim. Synthesis and characterization of novel ligand Type N2O2 and it's complexes with Cu (п) Co (п), Ni (п), Zn (п), and Cd (п) ions. Ibn al-Haitham Journal for Pure and Applied Science. 2009. Vol. 22, no. 2.
https://search.emarefa.net/detail/BIM-354900
Data Type
Journal Articles
Language
English
Notes
Includes appendices.
Record ID
BIM-354900