Synthesis, characterization, theoretical studies and bioactivity of Pd (II), Rh (III), Ru (III) and Pt (IV) complexes with 1, 8-naphthalimide derivative
Other Title(s)
تحضير و تشخيص و دراسة نظرية و فعالية بايولوجية لمعقدات الأيونات Pt (IV), Rh (III), Ru (III), Pd(II) مع مشتق 1، 8-نفثال ايماي
Joint Authors
Ibrahim, Sura Khalil
Abd, Asia Hamid
al-Hasani, Rihab Abd al-Mahdi
Source
Issue
Vol. 57, Issue 4B (31 Dec. 2016), pp.2575-2591, 17 p.
Publisher
University of Baghdad College of Science
Publication Date
2016-12-31
Country of Publication
Iraq
No. of Pages
17
Main Subjects
Topics
Abstract EN
A New Mannich base [N-(4-morpholinomethyl)-1,8-naphthalimide] (L), was synthesized and characterized by C.H.N analysis, FTIR, UV-Vis and 1HNMR spectral analysis.
Metal ion complexes of (L) with Pt(IV), Rh(III), Ru(III) and Pd(II) ions were prepared and characterized by FT-IR, and UV-Vis spectroscopy, elemental analysis (C.H.N), flame atomic absorption techniques as well as magnetic susceptibility and conductivity measurements.
The results showed that metal ion complexes for all complexes were found in [1:2] [M:L] ratio except for Pd(II) complex which was found in [1:1] [M:L] ratio.
Hyperchem-8 program has been used to predict structural geometries of the (L) and it's complexes in gas phase.
The electrostatic potential (EP) of the (L) was calculated.
Furthermore, the heat of formation ( ), binding energy ( ), vibration spectra, electronic spectra and bond length for the ligand (L) and its metal ion complexes were calculated by PM3 methods.
The antimicrobial activity of (L) and its complexes has been extensively studied against pathogenic bacteria such as (Pseudonomous aerugionosa) as gram negative and (Bacillus Subtilis) as gram positive and fungi (Candida albicans) and (Aspergillus flavus) by agar-well diffusion technique.
American Psychological Association (APA)
al-Hasani, Rihab Abd al-Mahdi& Abd, Asia Hamid& Ibrahim, Sura Khalil. 2016. Synthesis, characterization, theoretical studies and bioactivity of Pd (II), Rh (III), Ru (III) and Pt (IV) complexes with 1, 8-naphthalimide derivative. Iraqi Journal of Science،Vol. 57, no. 4B, pp.2575-2591.
https://search.emarefa.net/detail/BIM-728818
Modern Language Association (MLA)
al-Hasani, Rihab Abd al-Mahdi…[et al.]. Synthesis, characterization, theoretical studies and bioactivity of Pd (II), Rh (III), Ru (III) and Pt (IV) complexes with 1, 8-naphthalimide derivative. Iraqi Journal of Science Vol. 57, no. 4B (2016), pp.2575-2591.
https://search.emarefa.net/detail/BIM-728818
American Medical Association (AMA)
al-Hasani, Rihab Abd al-Mahdi& Abd, Asia Hamid& Ibrahim, Sura Khalil. Synthesis, characterization, theoretical studies and bioactivity of Pd (II), Rh (III), Ru (III) and Pt (IV) complexes with 1, 8-naphthalimide derivative. Iraqi Journal of Science. 2016. Vol. 57, no. 4B, pp.2575-2591.
https://search.emarefa.net/detail/BIM-728818
Data Type
Journal Articles
Language
English
Notes
Text in English ; abstracts in English and Arabic.
Record ID
BIM-728818