Synthesis, spectral and dyeing performance studies of 4-(2-Aminmo-5-Nitro-Phenylazo)-1, 5-Dimethyl-2-Phenyl-1, 2-Dihydro-Pyrazol-3-one complexes with some metal ions
Other Title(s)
تحضير و دراسة طيفية لمعقدات بعض الأيونات الفلزية مع 2-أمينو-5-نايترو فنيل ازو)-1، 5-ثنائي مثيل- 2 فنيل-2، 1-ثنائي هايدرو-بايرازول-3-اون و متابعة أدائها كصبغات
Author
Source
Issue
Vol. 13, Issue 4 (31 Dec. 2016), pp.838-845, 8 p.
Publisher
University of Baghdad College of Science for Women
Publication Date
2016-12-31
Country of Publication
Iraq
No. of Pages
8
Main Subjects
Topics
Abstract EN
The ligand 4-(2-aminmo-5-nitro-phenylazo)-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-one derived from 4-aminoantipyrine and 4-nitroaniline was synthesized.
The synthesized ligand was characterized by 1HNMR, FT-IR, UV-Vis spectra and (C.H.N) analysis.
Complexes of (YIII and LaIII ) with the ligand were prepared in aqueous ethanol with a 1:2 M:L ratio and at optimum pH.
The prepared complexes were characterized by using flame atomic absorption, FT-IR, UV-Vis spectra,(C.H.N) analysis and conductivity measurement.
The stoichiometry of complexes was studied by the mole ratio and job methods.
A concentration range (1×10-4 - 3×10-4 M) obeyed Beer's law, the complex solutions show high values of molar absorption.
On the basis of physicochemical data octahedral geometries were attributed for the complexes.
All prepared compounds exhibited good antibacterial activity, the ligand and their complexes were application to cotton fabric and study of the detergent fastness.
American Psychological Association (APA)
Jarad, Amir Jabbar. 2016. Synthesis, spectral and dyeing performance studies of 4-(2-Aminmo-5-Nitro-Phenylazo)-1, 5-Dimethyl-2-Phenyl-1, 2-Dihydro-Pyrazol-3-one complexes with some metal ions. Baghdad Science Journal،Vol. 13, no. 4, pp.838-845.
https://search.emarefa.net/detail/BIM-734585
Modern Language Association (MLA)
Jarad, Amir Jabbar. Synthesis, spectral and dyeing performance studies of 4-(2-Aminmo-5-Nitro-Phenylazo)-1, 5-Dimethyl-2-Phenyl-1, 2-Dihydro-Pyrazol-3-one complexes with some metal ions. Baghdad Science Journal Vol. 13, no. 4 (2016), pp.838-845.
https://search.emarefa.net/detail/BIM-734585
American Medical Association (AMA)
Jarad, Amir Jabbar. Synthesis, spectral and dyeing performance studies of 4-(2-Aminmo-5-Nitro-Phenylazo)-1, 5-Dimethyl-2-Phenyl-1, 2-Dihydro-Pyrazol-3-one complexes with some metal ions. Baghdad Science Journal. 2016. Vol. 13, no. 4, pp.838-845.
https://search.emarefa.net/detail/BIM-734585
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 843-845
Record ID
BIM-734585