Synthesis and characterization of some metal complexes with (3Z ,5Z, 8Z)-2-azido-8-[azido (3Z,5Z)-2-azido-2,6-bis (azidocarbouyl) -8,9-dihydro-2H-l,7-dioxa-3,4,5-triazoniue-9-yl] methyl]-9-[(l-azido-l-hydroxy) methyl]-2H-l, 7-dioxa-3,4,5-triazouine-2,6-dicarbouylazide (L-AZ)
Joint Authors
Tahir, Thurayya A.
Mahdi, Walid K.
al-Waswi, Falih Hasan Musa Muhammad
Source
Ibn al-Haitham Journal for Pure and Applied Science
Issue
Vol. 30, Issue 3 (31 Dec. 2017), pp.77-90, 14 p.
Publisher
University of Baghdad College of Education for Pure Science / Ibn al-Haitham
Publication Date
2017-12-31
Country of Publication
Iraq
No. of Pages
14
Main Subjects
Natural & Life Sciences (Multidisciplinary)
Abstract EN
The reaction of LAs-Cl8 : [ (2.2- (l-(3.4-bis(carboxylicdichloromethoxy)-5-oxo-2.5- diliydrofuran-2-yl)ethane - 1.2-diyl)bis(2.2-dichloroacetic acid)]with sodium azide in ethanol with drops of distilled water has been investigated .
The new product L-AZ :(3Z .5Z.8Z)-2- azido-8-[azido(3Z.5Z)-2-azido-2.6-bis(azidocarbonyl)-8.9-dihydro-2H-1.7-dioxa-3.4.5- triazonine-9-yl]methyl]-9-[(l-azido-l-hydroxy)methyl]-2H-l,7-dioxa-3.4,5-triazonine - 2.6 - dicarbonylazide was isolated and characterized by elemental analysis (C.H.N) .
!H-NMR , Mass spectrum and Fourier transform infrared spectrophotometer (FT-IR) .
The reaction of the L-AZ withM+n: [ ( VO(II) .
Cr(III) .Mn(II) .
Co(II) .
Ni(II) .
Cu(II) .
Zn(II) .
Cd(II) and Hg(II)] has been investigated and was isolated and characterized by FT- IR .
UV-Visible .electrical conductivity, magnetic susceptibilities at 22 C° .
Atomic absorption and molar ratio Spectroscopic evidence showed that the binding of metal ions were through the azide(f.i- I.I-N3) Triazonine(3.5 -N3) and carboxyl moieties .
resulting in a six - coordinating metal ions (Cr(ni).Mn(II).Co(II).Ni(II) and Cu(II) ) .The VO(II) , Zn(II) .Cd(II).
andHg(E) were coordinated through azido Q1-I.I-N3) .
triazonine(3.5-N3) only forming square pyramidal for VO(II) and tetrahedral geometry for Zn(II) , Cd(II) .and Hg(II)β,B for Ni(II) , Cr(m) complexes were calculated too .
The molar ratio and metal estimation showed .
the ratio of L- AZ to metal ions was (10:1) ; (M/L)
American Psychological Association (APA)
Tahir, Thurayya A.& Mahdi, Walid K.& al-Waswi, Falih Hasan Musa Muhammad. 2017. Synthesis and characterization of some metal complexes with (3Z ,5Z, 8Z)-2-azido-8-[azido (3Z,5Z)-2-azido-2,6-bis (azidocarbouyl) -8,9-dihydro-2H-l,7-dioxa-3,4,5-triazoniue-9-yl] methyl]-9-[(l-azido-l-hydroxy) methyl]-2H-l, 7-dioxa-3,4,5-triazouine-2,6-dicarbouylazide (L-AZ). Ibn al-Haitham Journal for Pure and Applied Science،Vol. 30, no. 3, pp.77-90.
https://search.emarefa.net/detail/BIM-851842
Modern Language Association (MLA)
Tahir, Thurayya A.…[et al.]. Synthesis and characterization of some metal complexes with (3Z ,5Z, 8Z)-2-azido-8-[azido (3Z,5Z)-2-azido-2,6-bis (azidocarbouyl) -8,9-dihydro-2H-l,7-dioxa-3,4,5-triazoniue-9-yl] methyl]-9-[(l-azido-l-hydroxy) methyl]-2H-l, 7-dioxa-3,4,5-triazouine-2,6-dicarbouylazide (L-AZ). Ibn al-Haitham Journal for Pure and Applied Science Vol. 30, no. 3 (2017), pp.77-90.
https://search.emarefa.net/detail/BIM-851842
American Medical Association (AMA)
Tahir, Thurayya A.& Mahdi, Walid K.& al-Waswi, Falih Hasan Musa Muhammad. Synthesis and characterization of some metal complexes with (3Z ,5Z, 8Z)-2-azido-8-[azido (3Z,5Z)-2-azido-2,6-bis (azidocarbouyl) -8,9-dihydro-2H-l,7-dioxa-3,4,5-triazoniue-9-yl] methyl]-9-[(l-azido-l-hydroxy) methyl]-2H-l, 7-dioxa-3,4,5-triazouine-2,6-dicarbouylazide (L-AZ). Ibn al-Haitham Journal for Pure and Applied Science. 2017. Vol. 30, no. 3, pp.77-90.
https://search.emarefa.net/detail/BIM-851842
Data Type
Journal Articles
Language
English
Notes
Includes appendices : p. 85-90
Record ID
BIM-851842