Evidence of a Lead Metathesis Product from Calcium Hydroxyapatite Dissolution in Lead Nitrate Solution
Joint Authors
Saisa-ard, Oratai
Somphon, Weenawan
Dungkaew, Winya
Haller, Kenneth J.
Source
Advances in Materials Science and Engineering
Issue
Vol. 2014, Issue 2014 (31 Dec. 2014), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2014-02-03
Country of Publication
Egypt
No. of Pages
6
Abstract EN
Calcium hydroxyapatite, CaHAp, synthesized by the precipitation method, was utilized to study the calcium-lead metathesis reaction on dissolution in a lead nitrate solution under reflux conditions to prepare larger lead hydroxyapatite, PbHAp, crystals from CaHAp.
SEM images show development of crystalline PbHAp on the surfaces of CaHAp.
The needle-like crystal morphology observed for PbHAp after 24 h reaction time developed into hexagonal-rod crystal morphology within 48 h reaction time.
The largest PbHAp crystals obtained from 48 h reaction time have approximate size of 10 × 10 × 40 μm.
Powder X-ray diffraction results show mixed phases of CaHAp and PbHAp due to difficulty in separating the PbHAp product from the CaHAp substrate.
The PbHAp peaks observed after 24 h of reaction sharpen and increase in intensity after 48 h of reaction confirming that the PbHAp phase is the major product for the 48 h reaction time.
EDX results of the crystalline products show high intensity Pb peaks with lead to phosphorous ratio (5 : 3) as expected for PbHAp.
Lower intensity Ca peaks are also observed, consistent with incomplete coverage of the CaHAp growth substrate.
American Psychological Association (APA)
Saisa-ard, Oratai& Somphon, Weenawan& Dungkaew, Winya& Haller, Kenneth J.. 2014. Evidence of a Lead Metathesis Product from Calcium Hydroxyapatite Dissolution in Lead Nitrate Solution. Advances in Materials Science and Engineering،Vol. 2014, no. 2014, pp.1-6.
https://search.emarefa.net/detail/BIM-1015639
Modern Language Association (MLA)
Saisa-ard, Oratai…[et al.]. Evidence of a Lead Metathesis Product from Calcium Hydroxyapatite Dissolution in Lead Nitrate Solution. Advances in Materials Science and Engineering No. 2014 (2014), pp.1-6.
https://search.emarefa.net/detail/BIM-1015639
American Medical Association (AMA)
Saisa-ard, Oratai& Somphon, Weenawan& Dungkaew, Winya& Haller, Kenneth J.. Evidence of a Lead Metathesis Product from Calcium Hydroxyapatite Dissolution in Lead Nitrate Solution. Advances in Materials Science and Engineering. 2014. Vol. 2014, no. 2014, pp.1-6.
https://search.emarefa.net/detail/BIM-1015639
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1015639