Isolation and Characterisation of 2-Tert-butyl-8-hydroxyquinoline as a Crystalline Solid and Its Blue Fluorescent Li Complex
Joint Authors
Kathirgamanathan, Poopathy
Surendrakumar, Sivagnanasundram
Ravichandran, Seenivasagam
Blake, Alexander J.
Source
Advances in Materials Science and Engineering
Issue
Vol. 2014, Issue 2014 (31 Dec. 2014), pp.1-5, 5 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2014-02-04
Country of Publication
Egypt
No. of Pages
5
Abstract EN
2-Tert-butyl-8-hydroxyquinoline (2-TB-8-hq) has been isolated as a crystalline solid and its X-ray structure elucidated, resolving three decades of controversy, since it was previously wrongly reported as yellow oil by some other workers.
An improved synthetic method has been developed which increases the yield from 20% to 60%.
The lithium complex of 2-TB-8-hq is blue emitting and the HOMO and LUMO levels are lowered by 0.86 eV and 0.74 eV, respectively, compared with the parent lithium 8-hydroxyquinolinolate (Li 8-hq).
American Psychological Association (APA)
Kathirgamanathan, Poopathy& Surendrakumar, Sivagnanasundram& Ravichandran, Seenivasagam& Blake, Alexander J.. 2014. Isolation and Characterisation of 2-Tert-butyl-8-hydroxyquinoline as a Crystalline Solid and Its Blue Fluorescent Li Complex. Advances in Materials Science and Engineering،Vol. 2014, no. 2014, pp.1-5.
https://search.emarefa.net/detail/BIM-1015707
Modern Language Association (MLA)
Kathirgamanathan, Poopathy…[et al.]. Isolation and Characterisation of 2-Tert-butyl-8-hydroxyquinoline as a Crystalline Solid and Its Blue Fluorescent Li Complex. Advances in Materials Science and Engineering No. 2014 (2014), pp.1-5.
https://search.emarefa.net/detail/BIM-1015707
American Medical Association (AMA)
Kathirgamanathan, Poopathy& Surendrakumar, Sivagnanasundram& Ravichandran, Seenivasagam& Blake, Alexander J.. Isolation and Characterisation of 2-Tert-butyl-8-hydroxyquinoline as a Crystalline Solid and Its Blue Fluorescent Li Complex. Advances in Materials Science and Engineering. 2014. Vol. 2014, no. 2014, pp.1-5.
https://search.emarefa.net/detail/BIM-1015707
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1015707