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Corrosion Inhibition of Mild Steel in Acidic Media by 5′-Phenyl-2′,4′-dihydrospiro[indole-3,3′-pyrazol]-2(1H)-one
Joint Authors
Nalini, D.
Firdhouse, M. Jannathul
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-06-12
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
The inhibition effect of 5′-phenyl-2′,4′-dihydrospiro[indole-3,3′-pyrazol]-2(1H)-one (SPAH) on mild steel corrosion in 1 M HCl and 0.5 M H2SO4 has been studied by weight loss, effect of temperature, electrochemical techniques, and quantum chemical studies.
The inhibition efficiency increases with increasing concentration of inhibitor but decreases with increase in temperature.
The adsorption of inhibitor on mild steel surface has been found to obey Langmuir and Temkin’s adsorption isotherm.
Potentiostatic polarization results revealed that SPAH acts as mixed type inhibitor.
The values of activation energy (Ea), free energy of adsorption (ΔG∘), enthalpy of adsorption (ΔH), and entropy of adsorption (ΔS) were calculated.
Surface analysis (SEM) was also carried out to establish the mechanism of inhibitor on mild steel corrosion in acid medium.
Quantum chemical studies using DFT were employed to explain the experimental results obtained in this study and to further give insight into the inhibition action of SPAH on the mild steel surface.
American Psychological Association (APA)
Firdhouse, M. Jannathul& Nalini, D.. 2012. Corrosion Inhibition of Mild Steel in Acidic Media by 5′-Phenyl-2′,4′-dihydrospiro[indole-3,3′-pyrazol]-2(1H)-one. Journal of Chemistry،Vol. 2013, no. 2013, pp.1-9.
https://search.emarefa.net/detail/BIM-1031266
Modern Language Association (MLA)
Firdhouse, M. Jannathul& Nalini, D.. Corrosion Inhibition of Mild Steel in Acidic Media by 5′-Phenyl-2′,4′-dihydrospiro[indole-3,3′-pyrazol]-2(1H)-one. Journal of Chemistry No. 2013 (2013), pp.1-9.
https://search.emarefa.net/detail/BIM-1031266
American Medical Association (AMA)
Firdhouse, M. Jannathul& Nalini, D.. Corrosion Inhibition of Mild Steel in Acidic Media by 5′-Phenyl-2′,4′-dihydrospiro[indole-3,3′-pyrazol]-2(1H)-one. Journal of Chemistry. 2012. Vol. 2013, no. 2013, pp.1-9.
https://search.emarefa.net/detail/BIM-1031266
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1031266