Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]
Joint Authors
Ko, Il-Ju
Oh, Hyun-Chang
Cha, Yong-Jun
Han, Chae Hyeok
Choi, Eun-Young
Source
Advances in Materials Science and Engineering
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-08-28
Country of Publication
Egypt
No. of Pages
6
Abstract EN
The framework of [RMI]2[Co2(BTC)2(H2O)2] (RMI = 1-alkyl-3-methylimidazolium, alkyl; ethyl (EMI); propyl (PMI); butyl (BMI)), which has uniquely occurred in ionothermal reactions of metal salts and H3BTC (1,3,5-benzenetricarboxylic acid), an organic ligand, reappeared in this work.
Ionothermal reaction of cobalt acetate and H3BTC with [BMI]Br ionic liquid as the reaction medium yielded the novel coordination polymer [BMI]2[Co2(BTC)2(H2O)2] (compound B2).
Similar ionothermal reactions with different [EMI]Br and [PMI]Br as the reaction media have been previously reported to produce [EMI]2[Co3(BTC)2(OAc)2] (compound A1) and [PMI]2[Co2(BTC)2(H2O)2] (compound B1), respectively.
In contrast with the trinuclear secondary building unit of A1, the framework structure of B1 and B2 consists of dinuclear secondary building units in common, but with subtle distinction posed by the different size of the incorporated cations.
These structural differences amidst the frameworks showed interesting aspects, including guest and void volume, and were used to explain the chemical trend observed in the system.
Moreover, the physicochemical properties of the newly synthesized compound have been briefly discussed.
American Psychological Association (APA)
Ko, Il-Ju& Oh, Hyun-Chang& Cha, Yong-Jun& Han, Chae Hyeok& Choi, Eun-Young. 2017. Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]. Advances in Materials Science and Engineering،Vol. 2017, no. 2017, pp.1-6.
https://search.emarefa.net/detail/BIM-1123844
Modern Language Association (MLA)
Ko, Il-Ju…[et al.]. Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]. Advances in Materials Science and Engineering No. 2017 (2017), pp.1-6.
https://search.emarefa.net/detail/BIM-1123844
American Medical Association (AMA)
Ko, Il-Ju& Oh, Hyun-Chang& Cha, Yong-Jun& Han, Chae Hyeok& Choi, Eun-Young. Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]. Advances in Materials Science and Engineering. 2017. Vol. 2017, no. 2017, pp.1-6.
https://search.emarefa.net/detail/BIM-1123844
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1123844