Effects of α-ZrP on Crystallinity and Flame-Retardant Behaviors of PA6MCA Composites
Joint Authors
Xu, Jiayou
Huang, Siwen
Deng, Haiming
Xiao, Yuanfang
Source
International Journal of Polymer Science
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-12, 12 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-01-03
Country of Publication
Egypt
No. of Pages
12
Main Subjects
Abstract EN
Novel flame-retardant Polyamide6/Melamine cyanurate-alpha-zirconium phosphate (PA6/MCA-α-ZrP) composites were prepared via the incorporation of the modified MCA (MCA-α-ZrP) into PA6.
MCA-α-ZrP were synthesized through the self-assembly of α-ZrP, Melamine (ME), and cyanuric acid (CA) molecules.
The results of differential scanning calorimetry (DSC) and X-ray diffraction (XRD) showed that the incorporation of enough α-ZrP (30 wt% MCA) caused the increased crystallinity of PA6 and tended to form γ phase.
The thermogravimetric analysis (TGA) and heat distortion temperature (HDT) test illustrated that the α-ZrP could increase the residue and HDT values of PA6/MCA and showed a synergistic effect with MCA.
The combination of MCA and α-ZrP caused the enhancement of vertical burning test (UL-94) rating.
Cone calorimeter test (CCT) gave clear evidences that PA6/MCA-10α-ZrP composites with low heat release rate (HRR), low total heat release (THR), and high amounts of char residues after combustion compared with PA6/MCA and PA6/MCA-30α-ZrP.
What is more, excellent mechanical properties were kept even though MCA and α-ZrP were dispersed not as good as expected.
American Psychological Association (APA)
Xiao, Yuanfang& Xu, Jiayou& Huang, Siwen& Deng, Haiming. 2017. Effects of α-ZrP on Crystallinity and Flame-Retardant Behaviors of PA6MCA Composites. International Journal of Polymer Science،Vol. 2017, no. 2017, pp.1-12.
https://search.emarefa.net/detail/BIM-1169064
Modern Language Association (MLA)
Xiao, Yuanfang…[et al.]. Effects of α-ZrP on Crystallinity and Flame-Retardant Behaviors of PA6MCA Composites. International Journal of Polymer Science No. 2017 (2017), pp.1-12.
https://search.emarefa.net/detail/BIM-1169064
American Medical Association (AMA)
Xiao, Yuanfang& Xu, Jiayou& Huang, Siwen& Deng, Haiming. Effects of α-ZrP on Crystallinity and Flame-Retardant Behaviors of PA6MCA Composites. International Journal of Polymer Science. 2017. Vol. 2017, no. 2017, pp.1-12.
https://search.emarefa.net/detail/BIM-1169064
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1169064