Umpolung of π-allylpalladium complexes
Joint Authors
Patil, Nitin T.
Yamamoto, Yoshinori
Source
Issue
Vol. 1, Issue 1 (31 Mar. 2006), pp.13-23, 11 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2006-03-31
Country of Publication
Jordan
No. of Pages
11
Main Subjects
Topics
Abstract EN
It is widely accepted that π-allylpalladium complexes (η3-allylPdX, X = halides, OAc, OCOOR,…etc) act as an electrophile in nature allowing the attack of various nucleophiles (Nu-) leading to the formation of the allylated products (allyl-Nu).
However, in the presence of a reductant, the electrophilic reactivity of π-allylpalladium complexes is converted to nucleophilic one ; referred as umpolung.
In this review, the recent progress made in the palladium-catalyzed umpolung of π-allylpalladium complexes is described.
American Psychological Association (APA)
Patil, Nitin T.& Yamamoto, Yoshinori. 2006. Umpolung of π-allylpalladium complexes. Jordan Journal of Chemistry،Vol. 1, no. 1, pp.13-23.
https://search.emarefa.net/detail/BIM-290087
Modern Language Association (MLA)
Patil, Nitin T.& Yamamoto, Yoshinori. Umpolung of π-allylpalladium complexes. Jordan Journal of Chemistry Vol. 1, no. 1 (Mar. 2006), pp.13-23.
https://search.emarefa.net/detail/BIM-290087
American Medical Association (AMA)
Patil, Nitin T.& Yamamoto, Yoshinori. Umpolung of π-allylpalladium complexes. Jordan Journal of Chemistry. 2006. Vol. 1, no. 1, pp.13-23.
https://search.emarefa.net/detail/BIM-290087
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 23
Record ID
BIM-290087
