Synthesis and studies of 1, 2-bis (5−2thiolethylsuphide-1, 3, 4-oxadiazole-2yl) ethane and it's complexes with (M (II) : Cu, Ni, Co, Hg)
Other Title(s)
تحضير و دراسة 1، 2 ثنائي (5-2ثايول أثيل كبريتيد-1، 3، 4-أوكسادايزول-2-يل) أيثان و معقداتها مع M (II) : (Hg, Co, Ni, Cu)
Joint Authors
Muhammad, Hikmat A.
al-Waswi, Falih Hasan Musa Muhammad
Abd Allah, Ali I.
Source
Issue
Vol. 20, Issue 1 (31 Mar. 2009), pp.75-89, 15 p.
Publisher
University of Mosul College of Science
Publication Date
2009-03-31
Country of Publication
Iraq
No. of Pages
15
Main Subjects
Abstract AR
تم تحضير ليكاند جديد من نوع 1 ̅،2 ̅ ثنائي 5 ̿ (2 ̿-ثايول أثيل كبريتيد)-4، 3، 1-أوكسادايزول-2يل)-ايثان (BTESOE) من تفاعل 1 ̅،2 ̅ ثنائي 5 ̿ (2 ̿-كلور ايتابل-كبريتيد)-1-3-4-أوكسادايزول-2 يل)-ايثان لقد تم تشخيص الليكاند باستخدام تقنيات أطياف الامتصاص لأشعة تحت الحمراء (1H, 13C.n.m.r) و التوصيلة المولارية.
تم استخدام (BTESOE) لتحضير أربعة معقدات مع (M(II) : Hg, Co, Ni, Cu) و تم دراسة المعقدات مستخدما أطياف تحت الحمراء و فوق البنفسجية و المرئية و الامتصاص الذري و التوصيلية المولارية و الحساسية المغناطسية.
و قد بينت النتائج بأن المعقدات المحضرة تمتلك أشكال ثمانية السطوح.
Abstract EN
The new ligand 1, 2-bis (5−2 -thiolethysulphide) -1, 3, 4- oxadiazole-2yl (ethane BTESOE) was prepared from the reaction of 1-, 2- bis- (5 − 2 - chloro ethylsulphide) -1, 3 4 oxadiazol-2yl ethane with sodium sulphide in aqueous ethanol solution.
The ligand was characterized using IR, UV / Vis, 1 H-n.m.r, 13C-n.m.r, mass spectroscopies and molar conductivity.
BTESOE was employed to synthesize four complexes with metals (M (II), (Cu, Ni, Co and Hg), the complexes were studied using IR, UV / Vis, atomic spectroscopies, molar conductivity and magnetic susceptibilities techniques.
The results showed that each of these complexes has an octahedral geometry structures.
American Psychological Association (APA)
Muhammad, Hikmat A.& al-Waswi, Falih Hasan Musa Muhammad& Abd Allah, Ali I.. 2009. Synthesis and studies of 1, 2-bis (5−2thiolethylsuphide-1, 3, 4-oxadiazole-2yl) ethane and it's complexes with (M (II) : Cu, Ni, Co, Hg). Rafidain Journal of Science،Vol. 20, no. 1, pp.75-89.
https://search.emarefa.net/detail/BIM-331350
Modern Language Association (MLA)
Muhammad, Hikmat A.…[et al.]. Synthesis and studies of 1, 2-bis (5−2thiolethylsuphide-1, 3, 4-oxadiazole-2yl) ethane and it's complexes with (M (II) : Cu, Ni, Co, Hg). Rafidain Journal of Science Vol. 20, no. 1 (2009), pp.75-89.
https://search.emarefa.net/detail/BIM-331350
American Medical Association (AMA)
Muhammad, Hikmat A.& al-Waswi, Falih Hasan Musa Muhammad& Abd Allah, Ali I.. Synthesis and studies of 1, 2-bis (5−2thiolethylsuphide-1, 3, 4-oxadiazole-2yl) ethane and it's complexes with (M (II) : Cu, Ni, Co, Hg). Rafidain Journal of Science. 2009. Vol. 20, no. 1, pp.75-89.
https://search.emarefa.net/detail/BIM-331350
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 88-89
Record ID
BIM-331350
