Fluxional behaviour of phosphine complexes of tricarbonyl-η5-cyclopentadienylhydridotungsteni
Joint Authors
al-Allaf, Talal Ahmad Khalil
Smith, John D.
Source
Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series
Issue
Vol. 9, Issue 1 (31 Jul. 1994), pp.39-56, 18 p.
Publisher
Mutah University Deanship of Academic Research
Publication Date
1994-07-31
Country of Publication
Jordan
No. of Pages
18
Main Subjects
Abstract EN
Complexes of the general formula [W ( ή5-C5H5 ) ( CO ) nLH l, n = 2, L=PMe2H1, PEt2Ph, PMePh2, PMunPh2, PBun3, P(OPh) and n = l, L = Ph2PCH2CH2PPh2, have been iolated and chancteized by IR, NMR (IH, 13C, 31P) and mass spectroscopy.
Interconversion of and trans isomers has been studied by variable temperature IH NMR meas- urements and values of AH-and associated with isomerisation have been calculated.
The results are compared with those from analogous molybdenum complexes made previously by others.
American Psychological Association (APA)
al-Allaf, Talal Ahmad Khalil& Smith, John D.. 1994. Fluxional behaviour of phosphine complexes of tricarbonyl-η5-cyclopentadienylhydridotungsteni. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series،Vol. 9, no. 1, pp.39-56.
https://search.emarefa.net/detail/BIM-436741
Modern Language Association (MLA)
al-Allaf, Talal Ahmad Khalil& Smith, John D.. Fluxional behaviour of phosphine complexes of tricarbonyl-η5-cyclopentadienylhydridotungsteni. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series Vol. 9, no. 1 (Jul. 1994), pp.39-56.
https://search.emarefa.net/detail/BIM-436741
American Medical Association (AMA)
al-Allaf, Talal Ahmad Khalil& Smith, John D.. Fluxional behaviour of phosphine complexes of tricarbonyl-η5-cyclopentadienylhydridotungsteni. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series. 1994. Vol. 9, no. 1, pp.39-56.
https://search.emarefa.net/detail/BIM-436741
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 55-56
Record ID
BIM-436741
