High-Pressure Synthesis and Study of NO+NO3− and NO2+NO3− Ionic Solids
Joint Authors
Kuznetsov, A. Yu.
Dubrovinsky, L.
Source
Advances in Physical Chemistry
Issue
Vol. 2009, Issue 2009 (31 Dec. 2009), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2009-01-04
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Abstract EN
Nitrosonium-nitrate NO+NO3− and dinitrogen pentoxide NO2+NO3− ionic crystals were synthesized by laser heating of a condensed oxygen-rich O2-N2 mixture compressed to different pressures, up to 40 GPa, in a diamond anvil cell (DAC).
High-pressure/high-temperature Raman and X-ray diffraction studies of synthesized samples disclosed a transformation of NO+NO3− compound to NO2+NO3− crystal at temperatures above ambient and pressures below 9 GPa.
High-pressure experiments revealed previously unreported bands in Raman spectra of NO+NO3− and NO2+NO3− ionic crystals.
Structural properties of both ionic compounds are analyzed.
Obtained experimental results support a hypothesis of a rotational disorder of NO+ complexes in NO+NO3− and indicate a rotational disorder of ionic complexes in NO2+NO3− solid.
American Psychological Association (APA)
Kuznetsov, A. Yu.& Dubrovinsky, L.. 2009. High-Pressure Synthesis and Study of NO+NO3− and NO2+NO3− Ionic Solids. Advances in Physical Chemistry،Vol. 2009, no. 2009, pp.1-11.
https://search.emarefa.net/detail/BIM-452368
Modern Language Association (MLA)
Kuznetsov, A. Yu.& Dubrovinsky, L.. High-Pressure Synthesis and Study of NO+NO3− and NO2+NO3− Ionic Solids. Advances in Physical Chemistry No. 2009 (2009), pp.1-11.
https://search.emarefa.net/detail/BIM-452368
American Medical Association (AMA)
Kuznetsov, A. Yu.& Dubrovinsky, L.. High-Pressure Synthesis and Study of NO+NO3− and NO2+NO3− Ionic Solids. Advances in Physical Chemistry. 2009. Vol. 2009, no. 2009, pp.1-11.
https://search.emarefa.net/detail/BIM-452368
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-452368
