“Mohsite” of Colomba : Identification as Dessauite-(Y)‎

Abstract EN

During a reorganization of the mineralogical collection of Turin University, old samples of the so-called mohsite of Colomba were found.

“Mohsite” was discredited in 1979 by Kelly et al., as a result of some analyses performed on the equivalent material coming from the French region of Hautes-Alpes, but the original samples found in similar geological setting in Italy were lost and never analysed with modern equipment.

After more than a century, the rediscovered samples of Professor Colomba were analysed by means of SEM-EDS analysis, microRaman spectroscopy, and X-ray diffraction.

The results have demonstrated that the historical samples studied by Colomba are Pb-free dessauite-(Y), and pointed to an idealized crystal chemical formula (Sr0.70Na0.25Ca0.09)Σ=1.04 (Y0.62U0.18Yb0.09Sc0.08)Σ=0.97 Fe22+(Ti12.66Fe4.783+V0.263+)Σ=17.70O38 and unit-cell parameters a = 10.376(3) Å, c = 20.903(6) Å, and V = 1949(1) Å3.