Decoration of Carbon Nanotubes with CoO and Co Nanoparticles

Joint Authors

Niarchos, D.
Hariharan, S.
Boukos, N.
Panagiotopoulos, I.
Pal, S.
Tzitzios, V.
Tsitrouli, D.
Fardis, M.
Belesi, M.
Papavassiliou, G.

Source

Journal of Nanomaterials

Issue

Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-9, 9 p.

Publisher

Hindawi Publishing Corporation

Publication Date

2011-04-04

Country of Publication

Egypt

No. of Pages

9

Main Subjects

Engineering Sciences and Information Technology
Chemistry
Civil Engineering

Abstract EN

Multiwall carbon nanotubes (MWNTs) decorated with CoO nanocrystals were synthesized by in-situ thermal decomposition of Co(acac)2 in oleyl amine under reflux conditions open in the air.

The CoO/MWNTs composite material can be easily converted to metallic Co/MWNTs through annealing under reducing atmosphere (4% H2) at 500°C without any significant sintering effect.

The composite materials characterized by X-ray diffraction, transmission electron microscopy, and Nuclear Magnetic Resonance (NMR) spectroscopy.

The structural and morphological characterization shows that the CoO has cubic face (fcc) and the particles deposited uniformly on the external surface of the carbon nanotubes.

In the annealed materials, the NMR shows that the fcc and hcp metallic Co phases coexist with a significant percentage of stacking faults.

The magnetic measurements indicated that the CoO/MWNTs composite is largely composed of CoO nanoparticles with uncompensated surface spins.

The fluctuations of spins persist in partially reduced CoO grains as shown by nuclear spin-lattice relaxation measurements.

American Psychological Association (APA)

Belesi, M.& Panagiotopoulos, I.& Pal, S.& Hariharan, S.& Tsitrouli, D.& Papavassiliou, G.…[et al.]. 2011. Decoration of Carbon Nanotubes with CoO and Co Nanoparticles. Journal of Nanomaterials،Vol. 2011, no. 2011, pp.1-9.
https://search.emarefa.net/detail/BIM-463269

Modern Language Association (MLA)

Belesi, M.…[et al.]. Decoration of Carbon Nanotubes with CoO and Co Nanoparticles. Journal of Nanomaterials No. 2011 (2011), pp.1-9.
https://search.emarefa.net/detail/BIM-463269

American Medical Association (AMA)

Belesi, M.& Panagiotopoulos, I.& Pal, S.& Hariharan, S.& Tsitrouli, D.& Papavassiliou, G.…[et al.]. Decoration of Carbon Nanotubes with CoO and Co Nanoparticles. Journal of Nanomaterials. 2011. Vol. 2011, no. 2011, pp.1-9.
https://search.emarefa.net/detail/BIM-463269

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references

Record ID

BIM-463269