Binding of Coumarin 334 with β-Cyclodextrin and with C-Hexylpyrogallol[4]arene : Opposite Fluorescence Behavior
Joint Authors
Israel Vijayaraj Muthu Vijayan, Enoch
Sowrirajan, Chandrasekaran
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-13, 13 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-10-28
Country of Publication
Egypt
No. of Pages
13
Main Subjects
Abstract EN
We report here the structure of the host-guest complexes of Coumarin 334 (C334) with β-cyclodextrin (β-CD) and with C-hexylpyrogallol[4]arene (C-HPA) and the effect of acidity on the neutral-cation equilibrium of C334 in water and in the presence of the host molecules.
The structures of the host-guest complexes are proposed on the basis of the change of fluorescence on the addition of β-CD or C-HPA to C334 and by 2D ROESY spectroscopy.
Opposite fluorescence behaviors, that is, quenching of fluorescence in β-CD and enhancement of fluorescence in C-HPA are observed.
Time-resolved fluorescence analysis is done for the complexation, and biexponential decay pattern is observed.
The possible strong inclusion complexation with C-HPA is explained.
The ground and the excited state pKa values for the protonation equilibrium of C334 in water and the difficulty of protonation in the presence of the host molecules are discussed.
American Psychological Association (APA)
Sowrirajan, Chandrasekaran& Israel Vijayaraj Muthu Vijayan, Enoch. 2013. Binding of Coumarin 334 with β-Cyclodextrin and with C-Hexylpyrogallol[4]arene : Opposite Fluorescence Behavior. Journal of Spectroscopy،Vol. 2013, no. 2013, pp.1-13.
https://search.emarefa.net/detail/BIM-469800
Modern Language Association (MLA)
Sowrirajan, Chandrasekaran& Israel Vijayaraj Muthu Vijayan, Enoch. Binding of Coumarin 334 with β-Cyclodextrin and with C-Hexylpyrogallol[4]arene : Opposite Fluorescence Behavior. Journal of Spectroscopy No. 2013 (2013), pp.1-13.
https://search.emarefa.net/detail/BIM-469800
American Medical Association (AMA)
Sowrirajan, Chandrasekaran& Israel Vijayaraj Muthu Vijayan, Enoch. Binding of Coumarin 334 with β-Cyclodextrin and with C-Hexylpyrogallol[4]arene : Opposite Fluorescence Behavior. Journal of Spectroscopy. 2013. Vol. 2013, no. 2013, pp.1-13.
https://search.emarefa.net/detail/BIM-469800
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-469800