Synthesis and Characterization of [2-CH3CH2C6H4NH3]6P6O18⋅4H2O
Joint Authors
Rzaigui, Mohamed
al-Deyab, Salem Slayyem
Marouani, Houda
Source
Issue
Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2011-07-24
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
Single crystals of [2-CH3CH2C6H4NH3]6P6O18⋅4H2O are synthesized in aqueous solution by the interaction of cyclohexaphosphoric acid and 2-ethylaniline.
This compound crystallizes in the monoclinic system with P21/c space group the unit cell dimensions are: a=16.220(4) Å, b=10.220(5) Å, c=20.328(4) Å, β=113.24(3)∘, Z=2, and V=3096.5(18) Å3.
The atomic arrangement can be described by layers formed by cyclohexaphosphate anions P6O186− and water molecules connected by hydrogen bonds O–H⋯O.
These inorganic layers are developed around bc planes at x=1/2 and are interconnected by the H-bonds created by ammonium groups of organic cations.
All the hydrogen bonds, the van der Waals contacts and electrostatic interactions between the different entities give rise to a three-dimensional network in the structure and add stability to this compound.
The thermal behaviour and the IR spectroscopic studies of this new cyclohexaphosphate are discussed.
American Psychological Association (APA)
Marouani, Houda& al-Deyab, Salem Slayyem& Rzaigui, Mohamed. 2011. Synthesis and Characterization of [2-CH3CH2C6H4NH3]6P6O18⋅4H2O. ISRN Materials Science،Vol. 2011, no. 2011, pp.1-6.
https://search.emarefa.net/detail/BIM-473078
Modern Language Association (MLA)
Marouani, Houda…[et al.]. Synthesis and Characterization of [2-CH3CH2C6H4NH3]6P6O18⋅4H2O. ISRN Materials Science No. 2011 (2011), pp.1-6.
https://search.emarefa.net/detail/BIM-473078
American Medical Association (AMA)
Marouani, Houda& al-Deyab, Salem Slayyem& Rzaigui, Mohamed. Synthesis and Characterization of [2-CH3CH2C6H4NH3]6P6O18⋅4H2O. ISRN Materials Science. 2011. Vol. 2011, no. 2011, pp.1-6.
https://search.emarefa.net/detail/BIM-473078
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-473078