Simultaneous Photocatalytic Reduction of Cr(VI) and Oxidation of Benzoic Acid in Aqueous N-F-Codoped TiO2 Suspensions : Optimization and Modeling Using the Response Surface Methodology
Joint Authors
Antonopoulou, Maria
Giannakas, Aris
Konstantinou, Ioannis
Source
International Journal of Photoenergy
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-09-24
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
The simultaneous photocatalytic reduction of Cr(VI) and oxidation of benzoic acid (BA) in aqueous suspensions using N-F-codoped TiO2 and simulated solar irradiation were investigated in the present study.
Chemometric optimization tools such as response surface methodology (RSM) and experimental design were used to model and optimize selected operational parameters of the simultaneous photocatalytic reduction of Cr(VI) and oxidation of BA.
RSM was developed by considering a central composite design with three input variables, that are, N-F-codoped TiO2 mass, ratio of Cr/BA, and pH.
The removal of Cr(VI) and BA in binary systems, containing both Cr(VI) and BA, showed a synergistic photocatalytic decontamination as BA significantly facilitated Cr(VI) reduction, whereas Cr(VI) accelerated also BA degradation.
Due to the anionic-type adsorption onto TiO2 and its acid-catalyzed photocatalytic reduction, the removal of Cr(VI) decreased with increasing pH, while the degradation of BA followed also the same trend.
Under the optimum conditions (N-F-TiO2) = 600 mg L−1, ratio of Cr(VI)/BA = 5, pH = 4, the removal for both Cr and BA followed a pseudo first-order kinetic model.
It was found that the selected variables have significant effect both on Cr(VI) removal and BA degradation efficiency.
The results revealed the feasibility and the effectiveness of using N-F-codoped TiO2 as photocatalyst for simultaneous decontamination of Cr(VI) and organic pollutants such as BA due to the appropriate oxidation and reduction ability of the photogenerated h+VB-e−CB pairs.
American Psychological Association (APA)
Antonopoulou, Maria& Giannakas, Aris& Konstantinou, Ioannis. 2012. Simultaneous Photocatalytic Reduction of Cr(VI) and Oxidation of Benzoic Acid in Aqueous N-F-Codoped TiO2 Suspensions : Optimization and Modeling Using the Response Surface Methodology. International Journal of Photoenergy،Vol. 2012, no. 2012, pp.1-10.
https://search.emarefa.net/detail/BIM-478221
Modern Language Association (MLA)
Antonopoulou, Maria…[et al.]. Simultaneous Photocatalytic Reduction of Cr(VI) and Oxidation of Benzoic Acid in Aqueous N-F-Codoped TiO2 Suspensions : Optimization and Modeling Using the Response Surface Methodology. International Journal of Photoenergy No. 2012 (2012), pp.1-10.
https://search.emarefa.net/detail/BIM-478221
American Medical Association (AMA)
Antonopoulou, Maria& Giannakas, Aris& Konstantinou, Ioannis. Simultaneous Photocatalytic Reduction of Cr(VI) and Oxidation of Benzoic Acid in Aqueous N-F-Codoped TiO2 Suspensions : Optimization and Modeling Using the Response Surface Methodology. International Journal of Photoenergy. 2012. Vol. 2012, no. 2012, pp.1-10.
https://search.emarefa.net/detail/BIM-478221
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-478221