Effect of Hetero Atom on the Hammett’s Reaction Constant (ρ) from the Physical Basis of Dissociation Equilibriums of (Dithio) Benzoic Acids and (Thio) Phenols and Its Application to Solvolysis Reactions and Some Free Radical Reactions
Joint Authors
Rachuru, Sanjeev
Vandanapu, Jagannadham
Source
Advances in Physical Chemistry
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-4, 4 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-07-03
Country of Publication
Egypt
No. of Pages
4
Main Subjects
Abstract EN
The emergence of putative Hammett equation in mid 1930s was a boon to physical-organic chemists to elucidate the reaction mechanisms of several organic reactions.
Based on the concept of this equation several hundreds of papers have emerged in chemical literature in the last century on the effect of structure, on reactivity, and very few on thermodynamic stability and kinetic reactivity of intermediates.
In this article an attempt is made to explain the effect of hetero atom on Hammett’s reaction constant (ρ) taking the dissociation equilibriums of benzoic acids, dithiobenzoic acids, phenols, and thiophenols.
American Psychological Association (APA)
Vandanapu, Jagannadham& Rachuru, Sanjeev. 2012. Effect of Hetero Atom on the Hammett’s Reaction Constant (ρ) from the Physical Basis of Dissociation Equilibriums of (Dithio) Benzoic Acids and (Thio) Phenols and Its Application to Solvolysis Reactions and Some Free Radical Reactions. Advances in Physical Chemistry،Vol. 2012, no. 2012, pp.1-4.
https://search.emarefa.net/detail/BIM-483989
Modern Language Association (MLA)
Vandanapu, Jagannadham& Rachuru, Sanjeev. Effect of Hetero Atom on the Hammett’s Reaction Constant (ρ) from the Physical Basis of Dissociation Equilibriums of (Dithio) Benzoic Acids and (Thio) Phenols and Its Application to Solvolysis Reactions and Some Free Radical Reactions. Advances in Physical Chemistry No. 2012 (2012), pp.1-4.
https://search.emarefa.net/detail/BIM-483989
American Medical Association (AMA)
Vandanapu, Jagannadham& Rachuru, Sanjeev. Effect of Hetero Atom on the Hammett’s Reaction Constant (ρ) from the Physical Basis of Dissociation Equilibriums of (Dithio) Benzoic Acids and (Thio) Phenols and Its Application to Solvolysis Reactions and Some Free Radical Reactions. Advances in Physical Chemistry. 2012. Vol. 2012, no. 2012, pp.1-4.
https://search.emarefa.net/detail/BIM-483989
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-483989