Na3MP3O10·12H2O (M = Co, Ni) : Crystal Structure and IR Spectroscopy
Joint Authors
Essehli, Rachid
El Bali, Brahim
Dusek, Michal
Fejfarova, Karla
Mejdoubi, El Miloud
Azzaoui, Khalil
Source
International Journal of Inorganic Chemistry
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-11-27
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
Two new dodecahydrate trisodium triphosphates Na3MP3O10·12H2O (M = Co (1), Ni (2)) were synthesized using a wet chemistry route and characterized by X-ray diffraction and FT-IR spectroscopy.
They are isotypic, monoclinic (P21/n, Z=2), with pseudoorthorhombic unit cell parameters (Ǻ,°): (a=14,9906 (4), b=9,1628 (2), c=14,6660 (4), β=90,098 (2), for (1) and a=15,0236 (3), b=9,1972 (2), c=14,6654 (3), β=90,0492 (16) for (2)).
Values of R/Rw are 0.0267/0.0738 and 0.0284/0.0907, respectively, for (1) and (2).
Both compounds were found to be systematically twinned by 180° rotation around a.
Their frameworks are made by slabs parallel to ab plane, resulting from the cohesion of two kinds of metallic chains.
IR spectrum confirms the presence of characteristic bands from P3O10 phosphate group.
American Psychological Association (APA)
Azzaoui, Khalil& Essehli, Rachid& Mejdoubi, El Miloud& El Bali, Brahim& Dusek, Michal& Fejfarova, Karla. 2012. Na3MP3O10·12H2O (M = Co, Ni) : Crystal Structure and IR Spectroscopy. International Journal of Inorganic Chemistry،Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-491731
Modern Language Association (MLA)
Azzaoui, Khalil…[et al.]. Na3MP3O10·12H2O (M = Co, Ni) : Crystal Structure and IR Spectroscopy. International Journal of Inorganic Chemistry No. 2012 (2012), pp.1-6.
https://search.emarefa.net/detail/BIM-491731
American Medical Association (AMA)
Azzaoui, Khalil& Essehli, Rachid& Mejdoubi, El Miloud& El Bali, Brahim& Dusek, Michal& Fejfarova, Karla. Na3MP3O10·12H2O (M = Co, Ni) : Crystal Structure and IR Spectroscopy. International Journal of Inorganic Chemistry. 2012. Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-491731
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-491731