IR Spectra, Elastic and Dielectric Properties of Li–Mn Ferrite

Abstract EN

Polycrystalline ferrites, Li0.5–0.5xMnxFe2.5–0.5xO4, (where x= 0.0,0.1,0.3,0.5,0.7,0.9, and 1.0), were prepared by using ceramic method.

Single phase cubic structure was confirmed by X-ray diffractometer.

The lattice parameter “a” was found to increase with increasing Mn2+ ion substitution.

IR spectra of the samples were recorded from 200 to 1000 cm−1.

The two primary bands corresponding to tetrahedral υA and octahedral υB were observed at about 575 cm−1 and 370 cm−1, respectively.

Elastic properties of these mixed ferrites were estimated as a function of composition.

Young's modulus (E), rigidity modulus (G), bulk modulus (B), Debye temperature (θD), and mean sound velocity (Vm) were calculated from the transverse (Vt) and longitudinal (V1) wave velocities.

The variation of elastic moduli with composition was interpreted in terms of binding forces between the atoms of spinel lattice.

AC conductivity σ~ and dielectric properties of the samples were measured at room temperature over 100 Hz–1 MHz.

The electrical conduction mechanism could be explained with the electron hopping model.

Frequency exponential factor (s) was calculated and it was found between 0.4 and 0.8.