Using sulfadiazine derivatives as a new azodyes reagents for the complexation and determination of aluminum
Other Title(s)
استخدام مشتقات السلفادايزين ككواشف صبغية ازويه جديدة في تكوين المعقدات و تقدير الالمنيوم
Joint Authors
Ali, Asad Abbud
al-Yusufi, Haydar Abd al-Sattar
Source
Issue
Vol. 32, Issue 1C (30 Jun. 2014), pp.70-85, 16 p.
Publisher
University of Basrah College of Science
Publication Date
2014-06-30
Country of Publication
Iraq
No. of Pages
16
Main Subjects
Topics
Abstract AR
شملت ھذه الدراسھ لعملیة تعقیدیة لثلاث من مشتقات السلفادایزین الازویھ مھ الالمنیوم .ودرست سلوكیة المعقدات مما تؤكد تكون معقدات ازویھ مستقره .
ودرست الظروف المثلى لتكوین ھذه المقدات مثل تأثیر الزمن 12 ) و تاثیر تعاقبات الاضافھ .
ووجد ان - وتاثیر الدالھ الحامضیھ عند قیم مخلفة من الاس الھیدروجیني ( 2 2 ( فلز : لیكند ) عند اس ھیدروجیني 12 .
وتم تعیین معامل الامتصاص : التركیب الجزیئي للمعقدات 1 المولاري والامتصاصیھ والحساسیة ومدى انطباق قانو بیر .
ودرست تأثیر المتداخلات من الایونات الدخیلھ .
وحسب ثوابن الاستقراریھ ( التكوین ) باستخدام طریقة المحالیل المتناظره مستخدمین فیھا طریقة نصف الارتفاع
Abstract EN
This study involves the study of the complexation of three azodyes sulfadiazine derivatives, with aluminum.
The characterizations of complexes were studied, which confirming of forming stable azo dyes complexes.
The formation and stabilization of these complexes were studied by the optimum conditions, like time effect, pH effect at different values of pH (2-12) and sequence of additions.
The stoichiometry was found that the aluminium complexes form 1:2 (M:L) at pH value of 12.
The molar absorptivity coefficients, sensitivity and obeys of Beer's law were established .The interferences of others ions were also studied.
The stability (formation) constants of the complexes were determined by use of corresponding solutions method by aid of half-height method.
This method was found of good selectivity and high sensitivity for the determination of aluminum ions.
American Psychological Association (APA)
Ali, Asad Abbud& al-Yusufi, Haydar Abd al-Sattar. 2014. Using sulfadiazine derivatives as a new azodyes reagents for the complexation and determination of aluminum. Basrah Journal of Science،Vol. 32, no. 1C, pp.70-85.
https://search.emarefa.net/detail/BIM-516536
Modern Language Association (MLA)
Ali, Asad Abbud& al-Yusufi, Haydar Abd al-Sattar. Using sulfadiazine derivatives as a new azodyes reagents for the complexation and determination of aluminum. Basrah Journal of Science Vol. 32, no. 1C (2014), pp.70-85.
https://search.emarefa.net/detail/BIM-516536
American Medical Association (AMA)
Ali, Asad Abbud& al-Yusufi, Haydar Abd al-Sattar. Using sulfadiazine derivatives as a new azodyes reagents for the complexation and determination of aluminum. Basrah Journal of Science. 2014. Vol. 32, no. 1C, pp.70-85.
https://search.emarefa.net/detail/BIM-516536
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 83-84
Record ID
BIM-516536