تحضير المركبEthane dial bis ((5-methyl-1،3،4-oxadiazol-2-yl) hydrazine) و معقداته مع العناصر الانتقالية و دراستها نظريا
Joint Authors
حيدر عباس مهدي
فاطمة عبد الحسن
فليفل، إبراهيم عبود
Source
Issue
Vol. 13, Issue 1 (31 Mar. 2018), pp.1-9, 9 p.
Publisher
University of Thi-Qar Research and Development Department
Publication Date
2018-03-31
Country of Publication
Iraq
No. of Pages
9
Main Subjects
Abstract EN
The present work include preparation and characterization of ethane dial bis [(5-methyl-1,3,4-oxadiazol-2-yl)hydrazine] as ligand ,the new complexes were prepared from the reaction of ligand with the transition metal salts (CuCl2.6H2O, NiCl2.6H2O, CoCl.6H2O, FeCl3.6H2O, CrCl.6H2O).
The elemental analysis (C.H.N), Mass spectra, Infrared(IR) spectroscopy, Nuclear Magnetic Resonance Spectroscopy (1H-NMR), UV-Visible spectroscopy and molar conductivity techniques were used to characterize the structure formula of these ligand and their complexes.
The complexes of [Cr(III),Fe(III),Co(III)] for ligand have shown octahedral configuration.
Complexes of Ni(II) and Cu(II) have shown tetrahedral configuration, Semi-empirical method was used for calculating the Infrared spectra for the ligand and their complexes.
A comparison with the experimental data has also been done.
The Semi-empirical PM3 method was used in calculating the total energy (binding energy, complexation energy and the enthalpies of formation), bond length for the ligand and their metal complexes
American Psychological Association (APA)
فليفل، إبراهيم عبود وحيدر عباس مهدي وفاطمة عبد الحسن. 2018. تحضير المركبEthane dial bis ((5-methyl-1،3،4-oxadiazol-2-yl) hydrazine) و معقداته مع العناصر الانتقالية و دراستها نظريا. مجلة جامعة ذي قار،مج. 13، ع. 1، ص ص. 1-9.
https://search.emarefa.net/detail/BIM-811473
Modern Language Association (MLA)
فليفل، إبراهيم عبود....[و آخرون]. تحضير المركبEthane dial bis ((5-methyl-1،3،4-oxadiazol-2-yl) hydrazine) و معقداته مع العناصر الانتقالية و دراستها نظريا. مجلة جامعة ذي قار مج. 13، ع. 1 (آذار 2018)، ص ص. 1-9.
https://search.emarefa.net/detail/BIM-811473
American Medical Association (AMA)
فليفل، إبراهيم عبود وحيدر عباس مهدي وفاطمة عبد الحسن. تحضير المركبEthane dial bis ((5-methyl-1،3،4-oxadiazol-2-yl) hydrazine) و معقداته مع العناصر الانتقالية و دراستها نظريا. مجلة جامعة ذي قار. 2018. مج. 13، ع. 1، ص ص. 1-9.
https://search.emarefa.net/detail/BIM-811473
Data Type
Journal Articles
Language
Arabic
Notes
يتضمن مراجع ببليوجرافية : ص. 8-9
Record ID
BIM-811473