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Sequential Pd2(dba)3 participated C–C bond cleavage of O-bromophenyl cyclobutanones Michael addition en route to benzospirones
Joint Authors
Liu, Yu
Zhang, Long
Zhang, Miao
Fu, Liyan
Wu, Yunkai
Pei, Weibing
Ao, Yuhui
Zhang, Zhiwei
Source
Journal of Saudi Chemical Society
Issue
Vol. 23, Issue 1 (31 Jan. 2019), pp.7-12, 6 p.
Publisher
Publication Date
2019-01-31
Country of Publication
Saudi Arabia
No. of Pages
6
Main Subjects
Topics
Abstract EN
A tandem Pd2(dba)3 participated C–C bond cleavage of O-bromophenyl cyclobutanone derivatives/Michael addition reaction sequence was realized.
We disclosed the first intramolecular C–Br bond triggered ring opening reaction of arylcyclobutanones, distinct from related reports in which the reactions were initiated by arylboron, silane or unsaturated chemical motifs, among others.
The in situ generated palladium species underwent ring expansion process leading to methyleneindanones, which further reacted with dba to provide benzospirones in one step.
American Psychological Association (APA)
Fu, Liyan& Wu, Yunkai& Pei, Weibing& Ao, Yuhui& Zhang, Long& Zhang, Zhiwei…[et al.]. 2019. Sequential Pd2(dba)3 participated C–C bond cleavage of O-bromophenyl cyclobutanones Michael addition en route to benzospirones. Journal of Saudi Chemical Society،Vol. 23, no. 1, pp.7-12.
https://search.emarefa.net/detail/BIM-892702
Modern Language Association (MLA)
Fu, Liyan…[et al.]. Sequential Pd2(dba)3 participated C–C bond cleavage of O-bromophenyl cyclobutanones Michael addition en route to benzospirones. Journal of Saudi Chemical Society Vol. 23, no. 1 (Jan. 2019), pp.7-12.
https://search.emarefa.net/detail/BIM-892702
American Medical Association (AMA)
Fu, Liyan& Wu, Yunkai& Pei, Weibing& Ao, Yuhui& Zhang, Long& Zhang, Zhiwei…[et al.]. Sequential Pd2(dba)3 participated C–C bond cleavage of O-bromophenyl cyclobutanones Michael addition en route to benzospirones. Journal of Saudi Chemical Society. 2019. Vol. 23, no. 1, pp.7-12.
https://search.emarefa.net/detail/BIM-892702
Data Type
Journal Articles
Language
English
Notes
Includes margin notes : p. 12
Record ID
BIM-892702