Design of a Free-Ruthenium In2S3 Crystalline Photosensitized Solar Cell

المؤلفون المشاركون

Kang, Misook
Kwak, Byeong Sub
Im, Younghwan

المصدر

International Journal of Photoenergy

العدد

المجلد 2014، العدد 2014 (31 ديسمبر/كانون الأول 2014)، ص ص. 1-8، 8ص.

الناشر

Hindawi Publishing Corporation

تاريخ النشر

2014-07-06

دولة النشر

مصر

عدد الصفحات

8

التخصصات الرئيسية

الكيمياء

الملخص EN

A new type of sulfide-based, solid-state dye material that is sensitive to visible radiation was assessed as a potential replacement for commercial ruthenium complex dyes in a dye-sensitized solar cell (DSSC) assembly.

The In2S3 crystals on the surface of the TiO2 bottom blocking layer were grown as a solid-state dye material.

Scanning electron microscopy of In2S3 revealed a microsized, 3D-connected sheet-like shape, which was confirmed by X-ray diffraction to be a beta-structure.

The efficiency of the dye-sensitized solar cells assembled with a layer grown with In2S3 increased with increasing In2S3 mole concentrations to 0.05 M (1.02%) but decreased at concentrations greater than 0.6~0.8%.

This suggests that crystalline In2S3 acts as a dye sensitized to visible radiation, but the short-circuit current density is too low compared to the commercially available ruthenium dye.

This suggests that In2S3 crystals did not grow densely but were bulk-grown with large pores, resulting in a smaller amount of In2S3 per unit area.

Two IPCE curves were observed, which were assigned to TiO2 and In2S3, meaning that the TiO2 surfaces were covered completely with In2S3 crystals.

The exposure of TiO2 eventually leads to a reaction with the electrolytes, resulting in lower quantum efficiency.

نمط استشهاد جمعية علماء النفس الأمريكية (APA)

Kwak, Byeong Sub& Im, Younghwan& Kang, Misook. 2014. Design of a Free-Ruthenium In2S3 Crystalline Photosensitized Solar Cell. International Journal of Photoenergy،Vol. 2014, no. 2014, pp.1-8.
https://search.emarefa.net/detail/BIM-1036880

نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)

Kwak, Byeong Sub…[et al.]. Design of a Free-Ruthenium In2S3 Crystalline Photosensitized Solar Cell. International Journal of Photoenergy No. 2014 (2014), pp.1-8.
https://search.emarefa.net/detail/BIM-1036880

نمط استشهاد الجمعية الطبية الأمريكية (AMA)

Kwak, Byeong Sub& Im, Younghwan& Kang, Misook. Design of a Free-Ruthenium In2S3 Crystalline Photosensitized Solar Cell. International Journal of Photoenergy. 2014. Vol. 2014, no. 2014, pp.1-8.
https://search.emarefa.net/detail/BIM-1036880

نوع البيانات

مقالات

لغة النص

الإنجليزية

الملاحظات

Includes bibliographical references

رقم السجل

BIM-1036880