One-Pot Synthesis of Cu2OCu Self-Assembled Hollow Nanospheres with Enhanced Photocatalytic Performance

الملخص EN

Cu2O/Cu hollow spheres are prepared using one-pot template-free solvent-thermal synthesis route with (CH3COO)2Cu·H2O as a precursor.

With the reaction time increasing gradually from 2 h to 20 h, the morphology of the Cu2O/Cu evolves from nanoparticle to hollow nanosphere.

The hollow structure is obtained when the cooling rate falls down to 0.7°C/min.

And the content of Cu in the hollow spheres also can be easily controlled by adjusting the solvent-thermal synthesis time.

Using photocatalytic degradation of phenol as the probe molecules under visible-light illumination, we have investigated the influence of hollow structure on the photocatalytic activity of Cu2O/Cu.

The prepared hollow sphere Cu2O/Cu particles exhibited a higher photodegradation capability than nanoparticles and solid spheres.

When the content of Cu lies in the range of 11–86 wt%, the samples exhibit higher photocatalytic performance, indicating that the Cu2O/Cu particles with hollow structure are promising candidates for the processing of pollutants.