Studies on Hydrogenation of Liquid Natural Rubber Using Diimide

الملخص EN

Liquid natural rubber (LNR) is a depolymerized natural rubber (NR) which consists of shorter polymeric chains and lower molecular weight (Mw<105).

Hydrogenated LNR (HLNR) was synthesized via the thermal decomposition of p-toluenesulfonyl hydrazide (TSH) or 2,4,6-trimethylbenzenesulfonyl hydrazide (MSH).

The LNR and HLNR structures were characterized by Fourier-transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopies.

The percentage of hydrogenation was calculated from NMR spectrum.

The optimum percentage of hydrogenation (>90%) was achieved by manipulating the reaction parameters such as sources of diimide, TSH concentration, solvent, and reaction time.

The optimum condition was 3 : 1 weight ratio of TSH/LNR in o-xylene at 130°C in 4-hour reaction period.