A Kinetic and Mechanismic Study of Plasma-Induced Degradation of Monochloropropionic Acids in Water by Means of Anodic Contact Glow Discharge Electrolysis
المؤلفون المشاركون
Yang, Haiming
Zhao, Xiaotong
An, Baigang
Li, Lixiang
Wang, Shaoyan
Ju, Maowei
المصدر
International Journal of Polymer Science
العدد
المجلد 2016، العدد 2016 (31 ديسمبر/كانون الأول 2016)، ص ص. 1-8، 8ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2016-08-31
دولة النشر
مصر
عدد الصفحات
8
التخصصات الرئيسية
الملخص EN
Decomposition of aqueous monochloropropionic acids (MCPAs) was investigated by means of anodic contact glow discharge electrolysis (CGDE).
With the decay of MCPAs, the corresponding total organic carbon (TOC) also decreased smoothly.
Furthermore, it was found that chlorine atoms in the MCPAs were released as chloride ions.
As the main by-products, oxalic acid and formic acid were detected.
The acetic acid (CA), monochloroacetic acid (MCA), and propanedioic acid (PDA) were also detected as the primary intermediates for decomposition of the corresponding MCPAs.
The decay of both MCPAs and TOC obeyed the first-order kinetics, respectively.
The apparent rate constant for the decay of MCPAs increased with the increase in pKa values of MCPAs, while that for the decay of TOC was substantially unaffected.
The reaction pathway involving the successive attack of hydroxyl radical and the carbon chain cleavage were discussed based on the products and kinetics.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Yang, Haiming& Zhao, Xiaotong& An, Baigang& Li, Lixiang& Wang, Shaoyan& Ju, Maowei. 2016. A Kinetic and Mechanismic Study of Plasma-Induced Degradation of Monochloropropionic Acids in Water by Means of Anodic Contact Glow Discharge Electrolysis. International Journal of Polymer Science،Vol. 2016, no. 2016, pp.1-8.
https://search.emarefa.net/detail/BIM-1106889
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Yang, Haiming…[et al.]. A Kinetic and Mechanismic Study of Plasma-Induced Degradation of Monochloropropionic Acids in Water by Means of Anodic Contact Glow Discharge Electrolysis. International Journal of Polymer Science No. 2016 (2016), pp.1-8.
https://search.emarefa.net/detail/BIM-1106889
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Yang, Haiming& Zhao, Xiaotong& An, Baigang& Li, Lixiang& Wang, Shaoyan& Ju, Maowei. A Kinetic and Mechanismic Study of Plasma-Induced Degradation of Monochloropropionic Acids in Water by Means of Anodic Contact Glow Discharge Electrolysis. International Journal of Polymer Science. 2016. Vol. 2016, no. 2016, pp.1-8.
https://search.emarefa.net/detail/BIM-1106889
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-1106889
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
تقوم هذه الخدمة بالتحقق من التشابه أو الانتحال في الأبحاث والمقالات العلمية والأطروحات الجامعية والكتب والأبحاث باللغة العربية، وتحديد درجة التشابه أو أصالة الأعمال البحثية وحماية ملكيتها الفكرية. تعرف اكثر