h-BN-TiO2 Nanocomposite for Photocatalytic Applications

الملخص EN

h-BN-TiO2 nanocomposites were synthesized by the thermal hydrolysis of titanium peroxo-complexes in the presence of exfoliated h-BN.

The bulk h-BN was prepared by annealing mixture of boric acid and urea, and high intensity ultrasound was used for its exfoliation.

The prepared samples were characterized by X-ray powder diffraction (XRD), infrared spectroscopy, Raman spectroscopy, electron spin resonance (ESR), high resolution electron microscopy, BET surface area, and BJH porosity measurement.

The UV-Vis diffuse reflectance spectroscopy was employed to estimate band-gap energies.

The photoinduced charge on the surface of h-BN-TiO2 nanocomposites was visualized using electric force microscopy (EFM).

The photocatalytic activity was determined by azo dyes Orange II and Reactive Black 5 photobleaching.

The highest rate constant k = 0.0762 min−1 and 0.0164 min−1, under UV and visible light irradiation, respectively, showed sample denoted TiP050BN with moderate concentration of h-BN.