Metal-Organic Framework MIL-53(Fe)‎ as an Adsorbent for Ibuprofen Drug Removal from Aqueous Solutions: Response Surface Modeling and Optimization

الملخص EN

Ibuprofen contamination from water sources has been increasingly alarming due to its environmentally accumulative retention; however, the strategies for ibuprofen-containing water treatment are still an enormous challenge.

Herein, we described the utilization of metal-organic frameworks MIL-53(Fe) (MIL = Materials of Institute Lavoisier) for the adsorption of ibuprofen in synthetic solution.

Firstly, the MIL-53(Fe) was solvothemally synthesized and then characterized using the X-ray diffraction and Fourier-transform infrared spectroscopy techniques.

The optimization of ibuprofen adsorption over MIL-53(Fe) was performed with three independent variables including ibuprofen concentration (1.6–18.4 mg/L), adsorbent dosage (0.16–1.84 g/L), and pH (2.6–9.4) according to the experimental design from response surface methodology.

Under the optimized conditions, more than 80% of ibuprofen could be eliminated from water, indicating the promising potential of the MIL-53(Fe) material for treatment of this drug.

Kinetic and isotherm models also were used to elucidate the chemisorption and monolayer behavior mechanisms of ibuprofen over MIL-53(Fe).