Alkaline Ionic Liquid Modified PdC Catalyst as an Efficient Catalyst for Oxidation of 5-Hydroxymethylfurfural

الملخص EN

Conversion of HMF into FDCA was carried out by a simple and green process based on alkaline ionic liquid (IL) modified Pd/C catalyst (Pd/C-OH−).

Alkaline ionic liquids were chosen to optimize Pd/C catalyst for special hydrophilicity and hydrophobicity, redox stability, and unique dissolving abilities for polar compounds.

The Pd/C-OH− catalyst was successfully prepared and characterized by SEM, XRD, TG, FT-IR, and CO2-TPD technologies.

Loading of alkaline ionic liquid on the surface of Pd/C was 2.54 mmol·g−1.

The catalyst showed excellent catalytic activity in the HMF oxidation after optimization of reaction temperature, reaction time, catalyst amount, and solvent.

Supported alkaline ionic liquid (IL) could be a substitute and promotion for homogeneous base (NaOH).

Under optimal reaction conditions, high HMF conversion of 100% and FDCA yield of 82.39% were achieved over Pd/C-OH− catalyst in water at 373 K for 24 h.