PEDOT:PSS Overcoating Layer for Mechanically and Chemically Stable Ag Nanowire Flexible Transparent Electrode

الملخص EN

We investigated the effect of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) deposition on the chemical and mechanical stability of Ag nanowire flexible electrodes.

A large number of bending cycles, up to 500,000 cycles, were imposed on the Ag nanowire electrodes with and without PEDOT:PSS overcoating layer.

In situ resistance measurement during bending tests revealed that the Ag nanowire electrode with PEDOT:PSS overcoating layer was mechanically reliable, showing a 21.9% increase in resistance after 500,000 cycles of bending.

Scanning electron microscope images revealed that the failure of the Ag nanowire network occurred along with cracks initiated in the PEDOT:PSS layer, which resulted in the increase in resistance under bending.

Furthermore, the PEDOT:PSS deposition enhanced the chemical stability of Ag nanowire electrode, which showed no significant increase in resistance after exposure in air for 50 days.

Our study underscored that PEDOT:PSS is effective in protecting the Ag nanowires, while maintaining the high mechanical stability.