Preparation and Conductive and Electromagnetic Properties of Fe3O4PANI Nanocomposite via Reverse In Situ Polymerization

الملخص EN

In this paper, the magnetite/polyaniline (PANI) nanocomposite was prepared by the novel reverse in situ polymerization method.

Fe3O4 magnetic nanoparticles were synthesized in situ in PANI chloroform solution to form a suspension containing the Fe3O4/PANI nanocomposite.

It overcame the disadvantage of oxidation of the Fe3O4 by the oxidant in conventional method.

The Fe3O4/PANI chloroform suspension and the Fe3O4/PANI powder were characterized by FT-IR, TEM, XRD, vibrating sample magnetometer, Gouy magnetic balance, conductivity meter, and vector network analyzer.

It is demonstrated that the Fe3O4/PANI suspension has a good electrical conductivity that is up to 2.135 μS/cm at the optimal ratio of reactants.

The Fe3O4 nanoparticles are well dispersed in the PANI network with a particle size of about 10 nm.

Fe3O4/PANI powder has high saturation magnetization and magnetic susceptibility, as well as a broad application prospect in the field of electromagnetic devices.

The Fe3O4/PANI powder exhibits an excellent microwave absorption behavior, which can be an outstanding candidate for the rapid development of broadband shielding materials.