Effect of Nano-ppyOMMT on the Physical and Electrochemical Properties of an Ionic Liquid Gel Polymer Electrolyte

الملخص EN

A new type of nanopolypyrrole/organically modified montmorillonite-ionic liquid gel polymer electrolyte (ppy/OMMT-ILGPE) is prepared based on nanopolypyrrole/organically modified montmorillonite (ppy/OMMT), N-butyl-N- methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PP14TFSI), lithium-bis(trifluoromethanesulfonyl) (LiTFSI), polyvinylidene difluoride (PVDF), methyl methacrylate (MMA), and benzoyl peroxide (BPO) by an in situ method.

The effect of nano-ppy/OMMT on the physical and electrochemical properties of an ionic liquid gel polymer electrolyte is demonstrated.

The results show that nano-ppy/OMMT-ILGPE has a porous structure with a large surface area, and the diameter of the pores on the surface is approximately 1-2 μm.

The Li+ transference number of 0.72 is achieved, and the ionic conductivity reaches up to 1.2 × 10−3 S/cm at room temperature.

Nano-ppy/OMMT-ILGPE has good thermal stability and mechanical properties.

Meanwhile, nano-ppy/OMMT-ILGPE has fine cycle performance in the Li|nano-ppy/OMMT-ILGPE|LiNi1/3Co1/3Mn1/3O2 coin cell.

The good electrochemistry performance of nano-ppy/OMMT-ILGPE means that it can act as an ideal gel polymer electrolyte material for lithium ion batteries.