An electrical conductimetric study of association phenomena of 4-aminoantipyrine (4-AAp)‎ complexes in mixtures of methanol-water at different temperatures

الملخص EN

The aim of this work is to measure the electrical conductivity of Co (II) and Ni (II) complexes with 4-amino antipyrine in mixtures of different percentages of methanol and water at different temperatures.

The data were analyzed using the Lee-Wheaton equation for unsymmetrical electrolytes, the conductivity parameters : ionic equivalent conductivity λM2, association constant KA, and the distance parameter R are calculated.

The ionic equivalent conductivity λM2+, increases with increasing temperature, which may attributed to the breaking of hydrogen bonds between solvated ions.

Association constant KA increase with increasing temperature, which assumed the presences of simple columbic interactions between hard sphere ions in continuous medium.

The distance parameter R is calculated at the best fit values of standard deviation σΛ.

Thermodynamic parameters from the relation between LnKA and 1 \ T were calculated to examine the nature of interaction.

Walden product were calculated which show the variation depending on electrochemical equilibrium between ions and the solvent molecules with the composition of the mixed polar solvents.