A new statistical mechanical model for fluids : part ii. the close-packed fluid model

الملخص EN

Contact bond properties are to be determined in a close-packed fluid state (CPF).

Each molecule is trapped in a cage of Z other molecules forming Z contact bonds with the cage.

The sum of these bonds is the cage potential.

Semi-quantitative application of the Lennard-Jones 6-12 potential to these bonds suggested a parabolic function for the cage potential.

A suitable analytical function approximating the given results was found.

It has been used to get expressions for the energy properties of the contact bond.