Synthesis and crystal structure of thiocyanate bridged one dimensional polymeric complex of cadmium (II)‎

الملخص EN

A new one-dimensional polymeric complex [Cd(DMAB)2(SCN)2]n (DMAB = 4- Dimethylaminobenzaldehyde) (1) has been synthesized and characterized by elemental analyses, IR and single crystal X-ray crystallography.

It crystallizes in the monoclinic space group of P21/c with a = 5.8673(5) Å, b = 7.4615(8) Å, c = 25.411(2) Å, β = 91.9320(10)º, and Z = 2.

Crystal structure shows that the one-dimensional chain is propagated through doubly bridging thiocyanate and DMAB acts as terminal ligand.

Furthermore, thermal stability and luminescent property of 1 were investigated.