Synthesis and characterization of new ligand |(2-{l-[(2-hydroxy-benzyIidene) hydrazonoJ- ethyl} benzene-1,3, 5-triol] and Its complexes with (Mn(11), Fe(11), Cd(11), and Hg (11) ) Ions
العناوين الأخرى
تحضير و تشخيص لينكد جديد لقواعد شف benzyIidene)hydrazonoJ-ethyl} benzene-1, 3, 5-triolligand |(2-{l-[(2-hydroxy- و بعض معقداته مع الايوانات الفلزية (Mn(11), Fe(11), Cd(11), and Hg (11) )
المؤلفون المشاركون
al-Husayni, Ahmad Thabit Numan Husayn
Aziz, Manhal Rimun
al-Qazwini, Muhsin
المصدر
Ibn al-Haitham Journal for Pure and Applied Science
العدد
المجلد 21، العدد 3 (30 سبتمبر/أيلول 2008)، ص ص. 60-74، 15ص.
الناشر
جامعة بغداد كلية التربية ابن الهيثم
تاريخ النشر
2008-09-30
دولة النشر
العراق
عدد الصفحات
15
التخصصات الرئيسية
العلوم الطبيعية والحياتية (متداخلة التخصصات)
الملخص AR
in the present paper we report the synthesis of a new ligand -[H4L] [(2-{l-[(2-hydroxy-benzylidene)-hydrazono]-ethyl}ben2ene n\ and Hgni))؛l), Cd؛>and its complexes with (Mn(U), Fe اهمح-ق,و,ا The ligand w^s prepared in two steps .
In the first step a solution of salicylaldehyed in methanol reacted under reflux with hydrai'jnemonohydrate to give an intermediate compound which the second step with 2,4.6-trihydroxidemonohydrate giving ٢١؛ reacted the mentioned ligand .
The complexes were synthesis by direct reaction of the corresponding metal chloride with ligand .
The ligand ؛؛and the complexes have been characterized by spectroscopic method 1H NMR.
IR.
U.V-Vis, , atomic absorption!, HPLC microanalysis] along with conductivity measurements.
From the above data the أءا'(ات1<لام , ا (proposed molecular structures for complexes [Mn(H2L Were found to be an tetrahedral structure- ل(ات1ء)جل-ا] Cd(ILL)] , and about metal ions
الملخص EN
In the present paper we report the synthesis of a new ligand [H4L] [(2-{1-[(2-hydroxy-benzyl idene)-hydrazono]-ethy[} benzene- 1, 3, 5-triol and its complexes with (Mn(llJ, Fe(II), Cd(II).
and Hg(II)) The ligand was prepared in two steps.
In the first step a solution of salicylaldehyed in methanol reacted under reflux with hydrazinemonohydrate to give an intermediate compound which reacted in the second step with 2, 4, 6-trihydrox.idernonohydrate giving the mentioned ligand .
The complexes were synthesis by direct reaction of the corresponding metal chloride with ligand.
The ligand and the complexes have been characterized by spectroscopic methods ['H NMR, IR.
U.V-Vis, atomic absorption], HPLC microanalysis along with conductivity measurements.
From the above data the proposed molecular structures for complexes [Mn(H2L) J.
[Fe(HiL)], [Cd(HiL)], and [Hg(HaL)].
Were found to be an tetrahedral structure about metal ions.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
al-Husayni, Ahmad Thabit Numan Husayn& al-Qazwini, Muhsin& Aziz, Manhal Rimun. 2008. Synthesis and characterization of new ligand |(2-{l-[(2-hydroxy-benzyIidene) hydrazonoJ- ethyl} benzene-1,3, 5-triol] and Its complexes with (Mn(11), Fe(11), Cd(11), and Hg (11) ) Ions. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 21, no. 3, pp.60-74.
https://search.emarefa.net/detail/BIM-355431
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
al-Husayni, Ahmad Thabit Numan Husayn…[et al.]. Synthesis and characterization of new ligand |(2-{l-[(2-hydroxy-benzyIidene) hydrazonoJ- ethyl} benzene-1,3, 5-triol] and Its complexes with (Mn(11), Fe(11), Cd(11), and Hg (11) ) Ions. Ibn al-Haitham Journal for Pure and Applied Science Vol. 21, no. 3 (2008), pp.60-74.
https://search.emarefa.net/detail/BIM-355431
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
al-Husayni, Ahmad Thabit Numan Husayn& al-Qazwini, Muhsin& Aziz, Manhal Rimun. Synthesis and characterization of new ligand |(2-{l-[(2-hydroxy-benzyIidene) hydrazonoJ- ethyl} benzene-1,3, 5-triol] and Its complexes with (Mn(11), Fe(11), Cd(11), and Hg (11) ) Ions. Ibn al-Haitham Journal for Pure and Applied Science. 2008. Vol. 21, no. 3, pp.60-74.
https://search.emarefa.net/detail/BIM-355431
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes appendices : p. 67-73
رقم السجل
BIM-355431
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
تقوم هذه الخدمة بالتحقق من التشابه أو الانتحال في الأبحاث والمقالات العلمية والأطروحات الجامعية والكتب والأبحاث باللغة العربية، وتحديد درجة التشابه أو أصالة الأعمال البحثية وحماية ملكيتها الفكرية. تعرف اكثر