Synthesis and characterization of VO(II)‎, Cr(III)‎, Mn(II)‎, Fe(II)‎, Zn(II)‎, Cd(II)‎, Hg(II)‎ and UO2(VI)‎ complexes with ligands containing (ONO)‎ and (ON)‎ donor set atoms

الملخص EN

A new Schiff base o-hydroxybenzylidene-1-phenyl-2,3-dimethyl-4-amino-3-pyrazolin-5-on (HL) ,have been prepared and characterization.(HL) has been used as a chelating ligand to prepare a number of metal complexes VO(II) ,Cr(III) ,Mn(II),Fe(II),Hg(II) and UO2(II) .and mixed ligands complexes have been prepared between o-hydroxybenzylidene-1-phenyl-2,3-dimethyl-4-amino-3-pyrazolin-5-on and 8- hydroxy quinoline with VO(II),Zn(II),Cd(II), Hg(II) and UO2(II) the prepared complexes were isolated and characterized by (FT-IR)and (UV-Vis) spectroscopy.

Elemental analysis (C.H.N) Chloride contents, Flame atomic absorption technique.

in addition to magnetic susceptibility and conductivity measurement.

Molar ratio measurement in solution gave comparable results with those obtained from solid state study.