Electrochemical studies of triphenylphosphine, arsine and stibine-iron s-bonded thiocarboxylates in non-aqueous solutions

الملخص EN

The electrochemical behaviour of triphenylphoshine.

arsine and stibine derivatives of carbonyl cyclopentadienyliron S-bonded thiocarboxylate is studied using cyclic voltammetry.

The effects of various substituents on the electro oxidation and reduc tion potentials are investigated.

The incorporation of EPh3 (E=P, As, Sb) on Fe, ter- tiarybutyl (s) on cyclopentadiene, and various aliphatic or aromatic substrates on the thiocarboxylate group showed to result in systematic effects that were explained.