Synthesis, Spectroscopic Characterisation, and Biopotential and DNA Cleavage Applications of Mixed Ligand 4-N,N-Dimethylaminopyridine Metal Complexes
المؤلفون المشاركون
Dilip, C. Surendra
Manikandan, K.
Thiruneelakandan, R.
Subahashini, D. Rajalaxmi (a)
المصدر
العدد
المجلد 2013، العدد 2013 (31 ديسمبر/كانون الأول 2013)، ص ص. 1-16، 16ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2013-11-14
دولة النشر
مصر
عدد الصفحات
16
التخصصات الرئيسية
الملخص EN
The mixed ligand transition metal complexes of 4-N,N-dimethylaminopyridine (DP) and chloride as primary and secondary ligands with the general formula [M(DP)3Cl3]; M = Cr(III) and Fe(III); [M′(DP)4Cl2]M′ = Co(II), Ni(II), Cu(II), and Cd(II) were synthesized in a microwave oven.
The complexes were characterized by FT-IR and UV, 1HNMR, 13CNMR spectra, TG/DTG, and various physicoanalytical techniques.
From the magnetic moment measurements and the electronic spectral data, a distorted octahedral geometry was proposed for the complexes.
The complexes express similar trend of thermal behaviour such that they lose water of hydration initially with the subsequent emission of organic and inorganic fragments and leave left the metal oxides as residue.
The activation thermodynamic parameters, such as E*, ΔH*, ΔS*, and ΔG* of the metal complexes, illustrate the spontaneous formation of the complexes.
The antimicrobial studies against various pathogenic bacterial and fungal serums insist on that the enhanced potential of the complexes over their ligand and their biopotential properties increases with concentration.
The DNA interaction of the synthesized complexes on CT-DNA was investigated by UV-Vis spectroscopy, viscosity, thermal denaturation, and electroanalytical experiments and their binding constants (Kb) were also calculated.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Dilip, C. Surendra& Manikandan, K.& Subahashini, D. Rajalaxmi (a)& Thiruneelakandan, R.. 2013. Synthesis, Spectroscopic Characterisation, and Biopotential and DNA Cleavage Applications of Mixed Ligand 4-N,N-Dimethylaminopyridine Metal Complexes. Journal of Chemistry،Vol. 2013, no. 2013, pp.1-16.
https://search.emarefa.net/detail/BIM-453575
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Dilip, C. Surendra…[et al.]. Synthesis, Spectroscopic Characterisation, and Biopotential and DNA Cleavage Applications of Mixed Ligand 4-N,N-Dimethylaminopyridine Metal Complexes. Journal of Chemistry No. 2013 (2013), pp.1-16.
https://search.emarefa.net/detail/BIM-453575
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Dilip, C. Surendra& Manikandan, K.& Subahashini, D. Rajalaxmi (a)& Thiruneelakandan, R.. Synthesis, Spectroscopic Characterisation, and Biopotential and DNA Cleavage Applications of Mixed Ligand 4-N,N-Dimethylaminopyridine Metal Complexes. Journal of Chemistry. 2013. Vol. 2013, no. 2013, pp.1-16.
https://search.emarefa.net/detail/BIM-453575
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-453575
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
تقوم هذه الخدمة بالتحقق من التشابه أو الانتحال في الأبحاث والمقالات العلمية والأطروحات الجامعية والكتب والأبحاث باللغة العربية، وتحديد درجة التشابه أو أصالة الأعمال البحثية وحماية ملكيتها الفكرية. تعرف اكثر