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A Phenomenological Study on the Synergistic Role of Precious Metals in the Steam Reforming of Logistic Fuels on Trimetal-Supported Catalysts
المؤلفون المشاركون
Azad, Abdul-Majeed
Sundararajan, Desikan
المصدر
Advances in Materials Science and Engineering
العدد
المجلد 2010، العدد 2010 (31 ديسمبر/كانون الأول 2010)، ص ص. 1-12، 12ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2010-12-20
دولة النشر
مصر
عدد الصفحات
12
التخصصات الرئيسية
العلوم الهندسية و تكنولوجيا المعلومات
الملخص EN
Fuel processors are required to convert sulfur-laden logistic fuels (jet fuels, diesel, and coal) into fuel cell quality hydrogen-rich reformate with little or no sulfur for extended periods.
Sulfur poisons and deactivates the reforming catalyst, therefore, sulfur-tolerant catalysts ought to be developed.
In this paper, the development, characterization, and evaluation of a series of nanoscale ceria-supported reforming catalysts containing three noble metals in low concentration (1 wt% ≤ total metal loading ≤ 1.33 wt%) for the steam-reforming of kerosene (a JP-8 surrogate) are reported.
Their performance is quantified in terms of H2 yield, tolerance towards sulfur in the fuel, and the on-stream stability and compared with that of monometal and bimetal analogs under identical conditions.
Due to the inherent cooperative synergy, a trimetal catalyst was found far superior to its mono- and bimetallic analog containing same amount of the precious metal loading in terms of quality of the reformate (measured by H2 level in steady-state) as well as the catalyst longevity on-stream prior to deactivation.
At the same time a mechanistic correlation between the distinct role of a given precious metal and the extent of its loading in each of the formulations and quality of the corresponding desulfurized H2-rich reformate was discovered.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Azad, Abdul-Majeed& Sundararajan, Desikan. 2010. A Phenomenological Study on the Synergistic Role of Precious Metals in the Steam Reforming of Logistic Fuels on Trimetal-Supported Catalysts. Advances in Materials Science and Engineering،Vol. 2010, no. 2010, pp.1-12.
https://search.emarefa.net/detail/BIM-463661
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Azad, Abdul-Majeed& Sundararajan, Desikan. A Phenomenological Study on the Synergistic Role of Precious Metals in the Steam Reforming of Logistic Fuels on Trimetal-Supported Catalysts. Advances in Materials Science and Engineering No. 2010 (2010), pp.1-12.
https://search.emarefa.net/detail/BIM-463661
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Azad, Abdul-Majeed& Sundararajan, Desikan. A Phenomenological Study on the Synergistic Role of Precious Metals in the Steam Reforming of Logistic Fuels on Trimetal-Supported Catalysts. Advances in Materials Science and Engineering. 2010. Vol. 2010, no. 2010, pp.1-12.
https://search.emarefa.net/detail/BIM-463661
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-463661
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
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