Measurement and Optimization of Metal-Nanoparticle-Induced Luminescence Enhancement Factors in a Crossed-Optical Fiber Configuration

الملخص EN

A crossed-optical-fiber configuration comprised of silver nanoparticles covalently attached to the core of an optical fiber and labeled with luminescent ruthenium molecules is reported.

A second optical fiber was placed at right angle of the fiber containing the nanoparticle/ruthenium, to form a fiber-fiber junction, and it was used to detect the luminescence from the ruthenium molecules bound to the first fiber.

To employ the effect of metal-enhanced luminescence, the ruthenium complex was kept at an appropriate distance from the nanoparticles by polyelectrolyte spacer layers.

For silver nanospheres, nanotriangles and nanorods and for spacer-layer thicknesses from 2–14 nm luminescence-enhancement factors were determined.

A 27-fold luminescence enhancement was found when the ruthenium complex was placed 4 nm from silver nanotriangles.

Finally, a calibration curve for the oxygen dependence of luminescence intensities and lifetimes of ruthenium complex is presented suggesting that the oxygen sensing capabilities of the nanoengineered-ruthenium complex are maintained.