Minimizing Chloride Interferences Produced by Calcium Chloride in the Determination of Cd by Graphite Furnace Atomic Absorption Spectrometry
المؤلفون المشاركون
Waterlot, Christophe
Douay, Francis
المصدر
العدد
المجلد 2012، العدد 2012 (31 ديسمبر/كانون الأول 2012)، ص ص. 1-10، 10ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2012-10-14
دولة النشر
مصر
عدد الصفحات
10
التخصصات الرئيسية
الملخص EN
Cadmium concentrations in CaCl2 extracting solutions at various concentrations were determined by graphite furnace atomic absorption using two background correctors: the deuterium and the high-speed self-reversal background correction systems.
Under- and overestimation of the Cd absorbance signals in CaCl2 solutions were observed for concentrations greater than 0.005 M using the deuterium lamp while no important effect was observed using the other background correction system.
The analytical performance of the spectrometer for the determination of Cd was studied in 0.01 M CaCl2 solution and single extractions were performed using reference materials and contaminated soil samples.
Cadmium was determined using the two background correction systems and a third method, which consists of the use of the deuterium lamp without any chemical modifier, was added to the study.
The results showed that the third method was unable to determine Cd concentrations in the CaCl2 solution due to the presence of extractable arsenic and iron.
For solutions without any dilution or diluted with a very low dilution factor, the CaCl2-extractable Cd concentrations measured using the deuterium lamp were systematically below those found using the high-speed self-reversal method.
These differences were explained by the presence of chloride ions in the atomization step.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Waterlot, Christophe& Douay, Francis. 2012. Minimizing Chloride Interferences Produced by Calcium Chloride in the Determination of Cd by Graphite Furnace Atomic Absorption Spectrometry. ISRN Spectroscopy،Vol. 2012, no. 2012, pp.1-10.
https://search.emarefa.net/detail/BIM-470359
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Waterlot, Christophe& Douay, Francis. Minimizing Chloride Interferences Produced by Calcium Chloride in the Determination of Cd by Graphite Furnace Atomic Absorption Spectrometry. ISRN Spectroscopy No. 2012 (2012), pp.1-10.
https://search.emarefa.net/detail/BIM-470359
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Waterlot, Christophe& Douay, Francis. Minimizing Chloride Interferences Produced by Calcium Chloride in the Determination of Cd by Graphite Furnace Atomic Absorption Spectrometry. ISRN Spectroscopy. 2012. Vol. 2012, no. 2012, pp.1-10.
https://search.emarefa.net/detail/BIM-470359
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-470359
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
تقوم هذه الخدمة بالتحقق من التشابه أو الانتحال في الأبحاث والمقالات العلمية والأطروحات الجامعية والكتب والأبحاث باللغة العربية، وتحديد درجة التشابه أو أصالة الأعمال البحثية وحماية ملكيتها الفكرية. تعرف اكثر