Mass Spectrometry of Bis-Quinolizidine Alkaloids : FAB-MS of Oxo-Substituted Sparteines

الملخص EN

The unpublished in the literature FAB mass spectral fragmentation of seven oxosparteines (i.e., 2-oxosparteine, 15-oxosparteine, 17-oxosparteine, 2,17-dioxosparteine, 2,13-dioxosparteine, 2-oxo-13-hydroxysparteine, and 2-oxo-17-hydroxysparteine) is investigated.

Fragmentation pathways, elucidation of which was assisted by FAB/collision-induced dissociation (CID) mass spectra measurements, are discussed.

The data obtained create the basis for distinguishing positional isomers.