Heats of Solution of Liquid Solutes in Various Solvents

الملخص EN

The values of the heats of solution (2131 solutions) of different liquid solutes in organic and inorganic solvents were obtained from the literature data on the heat of mixing (ΔmixH) in the wide range of concentrations.

The limit values of the heat of solution of a solute (i) in a solvent (j) (ΔsolnHi/j) were calculated from the limit data of the dependence ΔmixH/xi versus xi at xi→0 and the values of that of a solute (j) in a solvent (i) (ΔsolnHj/i) from the limit data of the dependence ΔmixH/xj versus xj at xj→0, respectively.